| Identification | Back Directory | [Name]
(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS | [CAS]
325168-88-5 | [Synonyms]
S-Xylyl-Phanephos
(S)-xylyl-PHANEPHos, (S)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene
(S)-(+)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE ,CTH-(S)-3,5-XYLYL-PHANEPHOS
(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane,min.93%CTH-(S)-3,5-xylyl-PHANEPHOS
(S)-(+)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(S)-3,5-xylyl-PHANEPHOS
Tricyclo[8.2.2.2(4,7)]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[bis(3,5-dimethylphenyl)phosphine] stereoisomer | [Molecular Formula]
C48H50P2 | [MDL Number]
MFCD03840578 | [MOL File]
325168-88-5.mol | [Molecular Weight]
688.871 |
| Chemical Properties | Back Directory | [Melting point ]
234-238 °C | [Boiling point ]
785.2±60.0 °C(Predicted) | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
Powder | [color ]
white | [Optical Rotation]
[α]/D +61.0°, c = 0.1 in ethanol |
| Questions And Answer | Back Directory | [Reaction]
- Chiral ligand employed in the enantioselective hydrogenation of various ketones.
- Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
- Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
- Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.
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