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32679-02-0

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32679-02-0 Structure

32679-02-0 Structure
IdentificationBack Directory
[Name]

BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
[CAS]

32679-02-0
[Synonyms]

BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RH&
5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE
Bis(acetonitrile)(cyclooctadiene)rhodium tetrafluoroborate
Bis(acetonitrile)cycloocta-1,5-dienerhodium tetrafluoroborate
Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I) tetrafluorob...
acetonitrile,(1Z,5Z)-cycloocta-1,5-diene,rhodium,tetrafluoroborate
Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(1+) tetrafluoroborate
BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE ISO 9001：2015 REACH
[EINECS(EC#)]

231-291-4
[Molecular Formula]

C12H14BF4N2Rh
[MDL Number]

MFCD06798085
[MOL File]

32679-02-0.mol
[Molecular Weight]

375.97
Chemical PropertiesBack Directory
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

solid
[color ]

yellow
[Sensitive ]

Air Sensitive
[InChI]

1S/C8H12.2C2H3N.BF4.Rh/c1-2-4-6-8-7-5-3-1;2*1-2-3;2-1(3,4)5;/h1-2,7-8H,3-6H2;2*1H3;;/q;;;-1;+1/b2-1-,8-7-;;;;
[InChIKey]

KSMAFOANQHYEJG-SUESZSCISA-N
[SMILES]

[Rh+].CC#N.CC#N.F[B-](F)(F)F.C1CC=CCCC=C1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[TSCA ]

No
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Bis(acetonitrile)(1,5-cyclooctadiene)rhodium(I)tetrafluoroborate [Rh(cod)(MeCN)2]BF4 may be used as a catalyst for the rhodium(I)-catalyzed silylation of aryl iodides and bromides with tetraethoxysilanes to form aryl silanes such as (4-bromophenyl)triethoxysilane and 4-(triethoxysilyl)acetophenone.
[reaction suitability]

core: rhodium
reagent type: catalyst
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(ACETONITRILE)(1,5-CYCLOOCTADIENE)RHODIUM(I) TETRAFLUOROBORATE(32679-02-0)1HNMR
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