| Identification | Back Directory | [Name]
TRIMETHYL 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE | [CAS]
330680-46-1 | [Synonyms]
TRIMETHYL 2,2'
6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE
4,4',4''-trimethoxycarbonyl-2,2':6',2''-terpyridine
TRIMETHYL 2,2':6',2''-TERPYRIDINE-4,4',4''-TRICARBOXYLATE
methyl 2,6-bis(4-methoxycarbonylpyridin-2-yl)pyridine-4-carboxylate
2,2':6',2''-Terpyridine-4,4',4''-tricarboxylic Acid Trimethyl Ester
Trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate
[2,2':6',2''-Terpyridine]-4,4',4''-tricarboxylic acid, 4,4',4''-trimethyl ester | [Molecular Formula]
C21H17N3O6 | [MDL Number]
MFCD11042545 | [MOL File]
330680-46-1.mol | [Molecular Weight]
407.39 |
| Chemical Properties | Back Directory | [Melting point ]
239.0 to 243.0 °C | [Boiling point ]
603.8±55.0 °C(Predicted) | [density ]
1.300±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [form ]
powder | [pka]
0.47±0.42(Predicted) | [Appearance]
White to off-white Solid | [InChI]
InChI=1S/C21H17N3O6/c1-28-19(25)12-4-6-22-15(8-12)17-10-14(21(27)30-3)11-18(24-17)16-9-13(5-7-23-16)20(26)29-2/h4-11H,1-3H3 | [InChIKey]
YDXTYOYBYASPDS-UHFFFAOYSA-N | [SMILES]
C1(C2=NC(C3=NC=CC(C(OC)=O)=C3)=CC(C(OC)=O)=C2)=NC=CC(C(OC)=O)=C1 |
| Hazard Information | Back Directory | [Synthesis]
3.65 g (10.0 mmol) of [2,2':6',2''-terpyridine]-4,4',4''-tricarboxylic acid (supplied by Tateyama Kasei) was placed in a 500 mL eggplant flask. 5 mL of concentrated sulfuric acid and 300 mL of methanol were added to the flask and the mixture was heated to reflux for 6 hours. After completion of the reaction, the reaction solution was filtered and the resulting solid was dried under vacuum to give 3.42 g of trimethyl 2,2':6',2''-terpyridine-4,4',4''-tricarboxylate. | [References]
[1] Dalton Transactions, 2011, vol. 40, # 17, p. 4497 - 4504
[2] Chemical Communications, 1997, # 18, p. 1705 - 1706
[3] Journal of the American Chemical Society, 2001, vol. 123, # 8, p. 1613 - 1624
[4] RSC Advances, 2013, vol. 3, # 48, p. 26035 - 26046
[5] Inorganica Chimica Acta, 2016, vol. 442, p. 158 - 166 |
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