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33558-14-4

33558-14-4 Structure

33558-14-4 Structure
IdentificationBack Directory
[Name]

Difluoromethylenetriphenylphosphorane
[CAS]

33558-14-4
[Synonyms]

Difluoromethylenetriphenylphosphorane
difluoromethylidenetriphenylphosphorane
Phosphorane, (difluoromethylene)triphenyl- (8CI,9CI)
[Molecular Formula]

C19H15F2P
[MDL Number]

MFCD17013293
[MOL File]

33558-14-4.mol
[Molecular Weight]

312.29
Chemical PropertiesBack Directory
[Boiling point ]

432.5±28.0 °C(Predicted)
[density ]

1.20±0.1 g/cm3(Predicted)
Hazard InformationBack Directory
[Uses]

Difluoromethylenetriphenylphosphorane is utilized for the introduction of =CF2 into organic compounds.
[Preparation]

Difluoromethylenetriphenylphosphorane is prepared in situ by the reaction of lithium or Sodium Chlorodifluoroacetate with  Triphenylphosphine (or, analogously, with Tri-n-butylphosphine); by the reaction of  Dibromodifluoromethane with 2 equiv of tertiary phosphines; or by the dehalogenation of  bromodifluoromethyltriphenylphosphonium bromide with tertiary phosphines or metals.
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