ChemicalBook--->CAS DataBase List--->339527-86-5

339527-86-5

339527-86-5 Structure

339527-86-5 Structure
IdentificationBack Directory
[Name]

POTASSIUM TETRACYANONICKELATE(II) HYDRATE
[CAS]

339527-86-5
[Synonyms]

Dipotassium nickel(2+) tetracyanide
(SP-4-1)-Tetrakis(cyano-κC)-nickelate(2-) dipotassium hydrate
[EINECS(EC#)]

238-082-7
[Molecular Formula]

C4 K2 N4 Ni . x H2 O
[MDL Number]

MFCD00150396
[MOL File]

339527-86-5.mol
[Molecular Weight]

240.94
Chemical PropertiesBack Directory
[Appearance]

Yellowish to orange crystalline powder
[Melting point ]

100℃ -H{2}O
[density ]

1.875 g/mL(lit.)
[vapor pressure ]

740 mmHg ( 25 °C)(lit.)
[form ]

crystal
[color ]

yellow
[Water Solubility ]

Soluble in water
[Major Application]

battery precursors
catalysts
material synthesis precursor
[InChI]

1S/4CN.2K.Ni.H2O/c4*1-2;;;;/h;;;;;;;1H2/q;;;;2*+1;-2;
[InChIKey]

LORCEWUZCQZQEK-UHFFFAOYSA-N
[SMILES]

[K+].[K+].[H]O[H].N#C[Ni--](C#N)(C#N)C#N
Hazard InformationBack Directory
[Chemical Properties]

Yellowish to orange crystalline powder
[Uses]


  • Electronic Structure: Study of the electronic structure of tetracyanonickelate(II) complexes, essential for applications in materials science and coordination chemistry (JJ Oppenheim, BJ McNicholas, J Miller, 2019).


Potassium tetracyanonickelate(II) hydrate can be used:
  • As a precursor for the synthesis of Hofmann-type metal-organic frameworks (MOFs) with high open metal sites density.
  • As a precursor in the synthesis of an anion-exchange resin for the removal of residual cyanide complexes in industrial plating wastewater.

[reaction suitability]

reagent type: catalyst
core: nickel
Safety DataBack Directory
[Hazard Codes ]

T,N,T+
[Risk Statements ]

49-15/29-22-42/43-50/53-32-26/27/28
[Safety Statements ]

53-22-36/37-43-45-61-60-29-28-7
[RIDADR ]

UN 1588 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

QR8650000
[TSCA ]

Yes
[HazardClass ]

6.1
[Storage Class]

6.1B - Non-combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 1 Dermal
Acute Tox. 2 Inhalation
Acute Tox. 2 Oral
Aquatic Acute 1
Aquatic Chronic 1
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