ChemicalBook--->CAS DataBase List--->34265-58-2

34265-58-2

34265-58-2 Structure

34265-58-2 Structure
IdentificationBack Directory
[Name]

ETHYL 2-HYDROXY-5-METHYLBENZOATE
[CAS]

34265-58-2
[Synonyms]

RARECHEM AL BI 0811
ETHYL 5-METHYLSALICYLATE
Ethyl 5-methylsalicylate 98%
2,5-Cresotic acid ethyl ester
ETHYL 2-HYDROXY-5-METHYLBENZOATE
Ethyl 6-hydroxy-3-methylbenzoate
5-Methylsalicylic acid ethyl ester
2-hydroxy-5-methyl-benzoicaciethylester
Benzoicacid,2-hydroxy-5-methyl-,ethylester
2-hydroxy-5-methyl-benzoic acid ethyl ester
[EINECS(EC#)]

251-903-3
[Molecular Formula]

C10H12O3
[MDL Number]

MFCD00192161
[MOL File]

34265-58-2.mol
[Molecular Weight]

180.2
Chemical PropertiesBack Directory
[Melting point ]

2℃
[Boiling point ]

251 °C(lit.)
[density ]

1.103 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.522(lit.)
[Fp ]

98 °F
[storage temp. ]

RT, stored under nitrogen
[pka]

10.23±0.18(Predicted)
[Appearance]

Light yellow to yellow Liquid
[InChI]

1S/C10H12O3/c1-3-13-10(12)8-6-7(2)4-5-9(8)11/h4-6,11H,3H2,1-2H3
[InChIKey]

ZGYXABNSOOACGL-UHFFFAOYSA-N
[SMILES]

CCOC(=O)c1cc(C)ccc1O
[EPA Substance Registry System]

Benzoic acid, 2-hydroxy-5-methyl-, ethyl ester (34265-58-2)
Safety DataBack Directory
[Hazard Codes ]

Xn
[Risk Statements ]

10-20/21/22-36/37/38
[Safety Statements ]

16-26-36
[RIDADR ]

UN 3272 3/PG 3
[WGK Germany ]

3
[TSCA ]

TSCA listed
[Storage Class]

3 - Flammable liquids
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Eye Irrit. 2
Flam. Liq. 3
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Ethyl 5-methylsalicylate (ethyl 2-hydroxy-5-methylbenzoate) is a hydroxyl benzoate derivative. One of the methods reported for its synthesis is the esterification of p-cresotinic acid with absolute alcohol. It is formed as an intermediate during the synthesis of 2-propoxy-5-methylbenzoic acid. Ethyl 2-hydroxy-5-methylbenzoate has been isolated as a minor by product in the AlCl3 promoted reaction of 2-methyl furan with ethyl propiolate.
[General Description]

Ethyl 5-methylsalicylate (ethyl 2-hydroxy-5-methylbenzoate) is a hydroxyl benzoate derivative. One of the methods reported for its synthesis is the esterification of p-cresotinic acid with absolute alcohol. It is formed as an intermediate during the synthesis of 2-propoxy-5-methylbenzoic acid. Ethyl 2-hydroxy-5-methylbenzoate has been isolated as a minor by product in the AlCl3 promoted reaction of 2-methyl furan with ethyl propiolate.
Spectrum DetailBack Directory
[Spectrum Detail]

ETHYL 2-HYDROXY-5-METHYLBENZOATE(34265-58-2)1HNMR
ETHYL 2-HYDROXY-5-METHYLBENZOATE(34265-58-2)IR
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