| Identification | Back Directory | [Name]
BUTOCARBOXIM | [CAS]
34681-10-2 | [Synonyms]
co755
CO 755
DRAWIN
Afiline
drawin755
Drawin 50
Co 755-d3
Drawin 755
BUTOCARBOXIM
Butocarboxime
ButocarboxiM-d3
-d3 Drawin 755-d3
Butocarboxim Solution
butocarboxim (bsi,iso)
BUTOCARBOXIM PESTANAL
SFNPDDSJBGRXLW-WEVVVXLNSA-N
Butocarboxim@1000 μg/mL in Methanol
3-METHYLTHIOBUTANONE O-METHYLCARBAMOYLOXIME
2-Methylthio-O-(N-methylcarbamoyl)-butanonoxim-3
3-(methylthio)-2-butanoneo-(methylcarbamoyl)oxime
3-(methylthio)-2-butanono-(n-methylcarbamoyl)oxime
3-(Methylthio)-2-butanone O-(methylcarbamoyl)oxime
2-Butanone,3-(methylthio)-,O-(N-methylcarbamoyl)oxime
3-(Methylthio)-2-butanone O-(Methyl-d3-carbaMoyl)oxiMe
2-Butanone, 3-(methylthio)-, O-(N-methylcarbamoyl)oxime
3-(methylthio)-2-butanoneo-((methylamino)carbonyl)oxime
3-(Methylthio)-O-((methylamino)carbonyl)oxime-2-butanone
3-(Methylthio)-2-butanone O-((methylamino)carbonyl)oxime
2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime
3-(Methylthio)-2-butanone O-[(Methyl-d3-aMino)carbonyl]oxiMe
(2E)-2-(([(Methylamino)carbonyl]oxy)imino)-3-(methylsulfanyl)butane
butocarboxim 3-(methylthio)-2-butanone O-[(methylamino)carbonyl]oxime | [EINECS(EC#)]
252-139-3 | [Molecular Formula]
C7H14N2O2S | [MDL Number]
MFCD00055326 | [MOL File]
34681-10-2.mol | [Molecular Weight]
190.26 |
| Chemical Properties | Back Directory | [Melting point ]
25 °C | [density ]
1.2118 (rough estimate) | [vapor pressure ]
1.1×10-2pa(20°C) | [refractive index ]
1.5690 (estimate) | [storage temp. ]
-20°C | [form ]
neat | [pka]
13.83±0.46(Predicted) | [Water Solubility ]
35 g l-1 (20 °C) | [Henry's Law Constant]
1.7×104 mol/(m3Pa) at 25℃, HSDB (2015) | [Major Application]
agriculture
environmental | [InChI]
1S/C7H14N2O2S/c1-5(6(2)12-4)9-11-7(10)8-3/h6H,1-4H3,(H,8,10)/b9-5+ | [InChIKey]
SFNPDDSJBGRXLW-WEVVVXLNSA-N | [SMILES]
CNC(=O)O\N=C(/C)C(C)SC | [EPA Substance Registry System]
2-Butanone, 3-(methylthio)-, O-[(methylamino)carbonyl]oxime (34681-10-2) |
| Safety Data | Back Directory | [Hazard Codes ]
T,N | [Risk Statements ]
10-23/24/25-36-50/53 | [Safety Statements ]
36/37-45-60-61 | [RIDADR ]
2757 | [WGK Germany ]
3 | [RTECS ]
EL9215000 | [HazardClass ]
6.1(b) | [PackingGroup ]
III | [Storage Class]
6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects | [Hazard Classifications]
Acute Tox. 3 Dermal
Acute Tox. 3 Inhalation
Acute Tox. 3 Oral
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Flam. Liq. 3 | [Hazardous Substances Data]
34681-10-2(Hazardous Substances Data) |
| Hazard Information | Back Directory | [Description]
Butocarboxim is a carbamate insecticide. It is highly soluble in water, highly volatile and is not expected to be persistent in soil systems depending upon local conditions. However, it may be persistent in waterbodies. Butocarboxin is highly toxic to birds and moderately toxic to most aquatic life. It is moderately toxic to mammals if ingested and is an irritant. | [Uses]
Butocarboxim is a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees in agric
ulture. | [Uses]
Labelled Butocarboxim, a systematic selectively acting insecticide with anticholinesterasic activity. Butocarboxim is used to control sucking pests such as mites, aphids, white flies as well as bees i
n agriculture. | [Production Methods]
The commercial production of butocarboxim involves the synthesis of its active oxime carbamate structure through a multi-step chemical process. Typically, it begins with the preparation of a thioether-substituted butanone intermediate, which is then reacted with hydroxylamine to form the oxime group. This intermediate is subsequently converted into the carbamate by reacting with methyl isocyanate or a similar carbamoylating agent. | [Mechanism of action]
Systemic with contact and stomach action. Acetylcholine esterase inhibitor. | [Metabolic pathway]
Butocarboxin is a structural isomer of aldicarb. Butoxycarboxim is the
sulfur oxidation (sulfone) product of butocarboxim. Limited information
is available to describe the degradation and metabolic fate of these two
compounds. As with aldicarb, oxidation of the sulfur molecule of butocarboxim
to butocarboxim sulfoxide and butoxycarboxim is the primary
photolytic and metabolic reaction in soils, plants and animals (Scheme 1). | [Degradation]
Butocarboxim (1) is stable to hydrolytic degradation (pH 5-7, up to 50 °C,
PM) and is stable under UV light irradiation. It degrades under strong
acidic and alkaline conditions.
Butoxycarboxim (2) is susceptible to alkaline hydrolysis (DT50 values of
500, 18 and 16 days in pH 5, 7 and 9, respectively, PM). It is also stable
under UV light irradiation. | [Pesticide Type]
Insecticide |
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