| Identification | Back Directory | [Name]
TIGLOYL CHLORIDE | [CAS]
35660-94-7 | [Synonyms]
Tiglyl chloride
TIGLOYL CHLORIDE
Tiglic acid chloride
(E)-2-methylcrotonoyl chloride
2-Methylcrotonic acid chloride
(E)-2-Methyl-2-butenoyl chloride
(2E)-2-Methylbut-2-enoyl chloride
(E)-2-METHYL-BUT-2-ENOYL CHLORIDE
(E)-2,3-Dimethylacryloyl chloride
TRANS-2-METHYL-2-BUTENOYL CHLORIDE
3-cis-Methyl-methacryloyl chloride
2-Butenoyl chloride, 2-Methyl-, (2E)-
(E)-2-Methyl-2-butenoic acid chloride
trans-2-Methyl-2-butenoyl chloride >=97.0%
(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chlo
(E)-2,3-Dimethylacryloyl chloride, (E)-2-Methylcrotonoyl chloride, 3-cis-Methyl-methacryloyl chloride, Tigloyl chloride | [EINECS(EC#)]
252-659-0 | [Molecular Formula]
C5H7ClO | [MDL Number]
MFCD00800725 | [MOL File]
35660-94-7.mol | [Molecular Weight]
118.56 |
| Chemical Properties | Back Directory | [Boiling point ]
145 °C | [density ]
1,08 g/cm3 | [refractive index ]
n20/D 1.471 | [Fp ]
22 °C | [storage temp. ]
Refrigerator | [solubility ]
soluble in Chloroform, Methanol | [form ]
clear liquid | [color ]
Colorless to Almost colorless | [InChI]
1S/C5H7ClO/c1-3-4(2)5(6)7/h3H,1-2H3/b4-3+ | [InChIKey]
TUNLYEHIVPWOHK-ONEGZZNKSA-N | [SMILES]
C\C=C(/C)C(Cl)=O |
| Safety Data | Back Directory | [Hazard Codes ]
T | [Risk Statements ]
10-23/24/25-34 | [Safety Statements ]
16-26-36/37/39-45 | [RIDADR ]
3265 | [WGK Germany ]
3 | [HazardClass ]
8/3 | [PackingGroup ]
II | [HS Code ]
2916199590 | [Storage Class]
3 - Flammable liquids | [Hazard Classifications]
Acute Tox. 3 Inhalation
Acute Tox. 4 Oral
Eye Dam. 1
Flam. Liq. 3
Skin Corr. 1B |
| Hazard Information | Back Directory | [Chemical Properties]
Clear Colourless Oil | [Uses]
Tigloyl Chloride is used in the polymerization of propylene as well as through a Freidel-Crafts reaction for the preparation of permethylindenyl complexes of transition metals. As well, it is primari ly used as a reagent in the enantioselective synthesis of dihydropyrans.
| [Synthesis Reference(s)]
Tetrahedron Letters, 18, p. 3379, 1977 DOI: 10.1016/S0040-4039(01)83244-5 |
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| Company Name: |
Energy Chemical
|
| Tel: |
021-021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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