| Identification | Back Directory | [Name]
6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL | [CAS]
35836-73-8 | [Synonyms]
(-)-NOPOL
2-((1R,5S)
(1R)-(-)-NOPOL
(1R)-(-)-Nopol,98%
(1R)-(-)-Nopol 98%
Dimethylbicyclohepteneethanol
6,6-DIMETHYL-2-NORPINENE-2-ETHANOL
-6,6-Dimethylbicyclo[3.1.1]hept-2-en-2-yl)
6,6-DIMETHYLBICYCLO(3.1.1)HEPT-2-ENE-2-ETHANOL
6,6Dimethyllbicyclo(3.1.1)hept-2-ene-2-ethanol
(-)-[(1R)-6,6-Dimethylnorpinane-2-ene]-2-ethanol
(1R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-ethanol
(1R)-6,6-DIMETHYLBICYCLO[3.1.1]HEPT-2-ENE-2-ETHANOL
(1R,5S)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol
(1α,5α)-7,7-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol
(1β,5β)-6,6-Dimethylbicyclo[3.1.1]hepta-2-ene-2-ethanol
Bicyclo3.1.1hept-2-ene-2-ethanol, 6,6-dimethyl-, (1R,5S)-
(1β,5β)-2-(2-Hydroxyethyl)-6,6-dimethylbicyclo[3.1.1]hepta-2-ene
(1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol
(-)-Nopol, (1R)-6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol, 6,6-Dimethyl-2-norpinene-2-ethanol, 6,6-Dimethylbicyclo[3.1.1]hept-2-ene-2-ethanol | [EINECS(EC#)]
252-744-2 | [Molecular Formula]
C11H18O | [MDL Number]
MFCD00075187 | [MOL File]
35836-73-8.mol | [Molecular Weight]
166.26 |
| Chemical Properties | Back Directory | [Appearance]
Clear colorless to light yellow liquid | [Boiling point ]
235-236 °C(lit.)
| [density ]
0.973 g/mL at 25 °C(lit.)
| [vapor pressure ]
2.17Pa at 20℃ | [refractive index ]
n20/D 1.493
| [Fp ]
210 °F
| [storage temp. ]
Refrigerator, under inert atmosphere | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Oil | [pka]
15.03±0.10(Predicted) | [color ]
Clear Colourless | [Optical Rotation]
[α]24/D 37°, neat | [Water Solubility ]
333.5mg/L at 20℃ | [Merck ]
14,6683 | [BRN ]
3196379 | [InChI]
1S/C11H18O/c1-11(2)9-4-3-8(5-6-12)10(11)7-9/h3,9-10,12H,4-7H2,1-2H3/t9-,10-/m0/s1 | [InChIKey]
ROKSAUSPJGWCSM-UWVGGRQHSA-N | [SMILES]
CC1(C)[C@H]2CC=C(CCO)[C@@H]1C2 | [LogP]
3.09 at 30℃ |
| Hazard Information | Back Directory | [Chemical Properties]
Clear colorless to light yellow liquid | [Uses]
(-)-Nopol, is a chiral building block used in chemical synthesis. It is an intermediate that can be used for the synthesis of bulky moiety-modified analogs to the sandalwood odorant Polysantol. | [Application]
(1R)-(-)-Nopol may be used in the preparation of optically active O,O-diterpenyl dithiophosphoric and O-terpenyl aryldithiophosphonic acids by reacting with tetraphosphorus decasulfide and 2,4-diaryl 1,3,2,4-dithiadiphosphetane-2,4-disulfides, respectively. It may also react with silver hexafluoroantimonate to form a complex, which can be an effective initiator for the nonthermal curing of epoxy resins by electron beam induced cationic polymerization. | [Definition]
ChEBI: (-)-Nopol is a monoterpenoid. | [General Description]
(1R)-(-)-Nopol is a chiral terpenol derivative. | [Hazard]
(1R)-(-)-Nopol has acute oral toxicity, it causes skin corrosion/irritation and serious eye damage/eye irritation.
| [Synthesis]
(1R)-(-)-Nopol can be synthesized under microwave irradiation conditions using β-pinene and paraformaldehyde as raw materials and solid superacid SO42-/ZrO2-TiO2 as a catalyst.
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| Company Name: |
J & K SCIENTIFIC LTD.
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| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
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400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
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| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
| Company Name: |
Sigma-Aldrich
|
| Telephone: |
021-61415566 800-8193336 |
| Website: |
https://www.sigmaaldrich.cn |
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