ChemicalBook--->CAS DataBase List--->371162-53-7

371162-53-7

371162-53-7 Structure

371162-53-7 Structure
IdentificationBack Directory
[Name]

LITHIUM TETRAKIS(PENTAFLUOROPHENYL)-
[CAS]

371162-53-7
[Synonyms]

Lithium tetrakis(pentafluorophenyl)borate's etherate
tetrakis(pentafluorophenyl)boron lithium ethyl etherate
Lithium tetrakis(pentafluorophenyl)borate(1-)-ethoxyethane(1:1:1)
Lithium tetrakis(pentafluorophenyl)borate compd. with 1,1'-oxybis[ethane] (2:5)
[Molecular Formula]

C28H10BF20LiO
[MDL Number]

MFCD01861289
[MOL File]

371162-53-7.mol
[Molecular Weight]

760.11
Chemical PropertiesBack Directory
[Melting point ]

118-122 °C
[InChIKey]

KPLZKJQZPFREPG-UHFFFAOYSA-N
[SMILES]

O(CC)CC.[B+3]([C-]1=C(C(F)=C(F)C(F)=C1F)F)([C-]1=C(C(F)=C(F)C(F)=C1F)F)([C-]1=C(C(F)=C(F)C(F)=C1F)F)[C-]1=C(C(F)=C(F)C(F)=C1F)F.[Li+]
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)
GHS07
[Signal word ]

Warning
[Hazard statements ]

H315-H319-H335
[Precautionary statements ]

P261-P264-P271-P280-P302+P352-P305+P351+P338
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
[Hazard Classifications]

Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
Hazard InformationBack Directory
[Uses]

Lithium tetrakis(pentafluorophenyl)borate ethyl etherate can be used as:
  • A coordinating counter anion in electrochemical reactions along with transition metal catalysts to enhance their acidity or solubility.
  • A catalyst in the Baeyer-Villiger oxidation of cycloalkanones to obtain lactones in the presence of aqueous hydrogen peroxide and oxalic acid.
  • An activator in the synthesis of poly(norbornene ester)s.

[reaction suitability]

core: boron
reagent type: catalyst
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