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374067-50-2

374067-50-2 Structure

374067-50-2 Structure
IdentificationBack Directory
[Name]

Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
[CAS]

374067-50-2
[Synonyms]

(R)-Ru(OAc)2(DM-BINAP)
Ru(OAc)2[(R)-xylbinap]
Diacetato[(R)-2,2μ-bis[di(3,5-xylyl)phosphino]-1,1μ-binaphtyl]ruthenium(II)
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II)
Diacetato{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}ruthenium(II) Ru(OAc)2[(R)-xylbinap]
[Molecular Formula]

C56H54O4P2Ru
[MDL Number]

MFCD09753022
[MOL File]

374067-50-2.mol
[Molecular Weight]

956.08
Chemical PropertiesBack Directory
[Melting point ]

>100°C
[storage temp. ]

2-8°C
[Water Solubility ]

Insoluble in water
[form ]

Powder
[color ]

dark brown
[Sensitive ]

air sensitive
[InChIKey]

HDUAMHMUQGCXCT-UHFFFAOYSA-N
[SMILES]

CC1=O[Ru+2]23(O=C(C)[O-]2)(P(C2C=C(C)C=C(C)C=2)(C2C=C(C)C=C(C)C=2)C2=CC=C4C=CC=CC4=C2C2=C4C=CC=CC4=CC=C2P3(C2C=C(C)C=C(C)C=2)C2C=C(C)C=C(C)C=2)[O-]1
[CAS DataBase Reference]

374067-50-2
Safety DataBack Directory
[Symbol(GHS) ]

Flame (GHS02)Exclamation Mark (GHS07)
GHS02,GHS07
[Signal word ]

Danger
[Hazard statements ]

H332-H302-H413-H319-H315-H228-H312
[Precautionary statements ]

P264-P280-P305+P351+P338-P337+P313P-P261-P271-P304+P340-P312-P280-P302+P352-P312-P322-P363-P501-P264-P280-P302+P352-P321-P332+P313-P362-P210-P240-P241-P280-P370+P378-P264-P270-P301+P312-P330-P501
[WGK Germany ]

3
[HS Code ]

2843.90.0000
[REACH Registrations]

Active
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reactions]

Catalyst system used for asymmetric hydrogenation. Reactions of 374067-50-2
Hazard InformationBack Directory
[Uses]

Takasago Ligands and Complexes for Asymmetric Reactions
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