| Identification | Back Directory | [Name]
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II) | [CAS]
374067-51-3 | [Synonyms]
(R)-Ru(OAc)2(H8-BINAP)
Diacetato[(R)-2,2μ-bis(diphenylphosphino)-5,5μ,6,6μ,7,7μ,8,8μ-octahydro-1,1μ-binaphthyl]ruthenium(II)
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthy]ruthenium(II)
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II),95%
Diacetato[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(R)-H8-binap] | [Molecular Formula]
C48H46O4P2Ru | [MDL Number]
MFCD09753023 | [MOL File]
374067-51-3.mol | [Molecular Weight]
851.91 |
| Chemical Properties | Back Directory | [Melting point ]
>100°C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
olive | [Sensitive ]
air sensitive | [InChIKey]
HZRBASMTZGJUJU-UHFFFAOYSA-L | [SMILES]
CC(=O)O[Ru]OC(C)=O.C1CCc2c(C1)ccc(P(c3ccccc3)c4ccccc4)c2-c5c6CCCCc6ccc5P(c7ccccc7)c8ccccc8 |
| Questions And Answer | Back Directory | [Reaction]
- Biaryl bisphosphine ligand. The H8-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP.
- The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.
|
| Hazard Information | Back Directory | [Uses]
(R)-Rutheniumdiacetate-(H8-BINAP) is used as a catalyst in the asymmetric hydrogenation of unsaturated carboxylic acids in supercritical carbon dioxide fluid. |
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