ChemicalBook--->CAS DataBase List--->3757-88-8

3757-88-8

3757-88-8 Structure

3757-88-8 Structure
IdentificationBack Directory
[Name]

PHENYLETHYNYLTRI-N-BUTYLTIN
[CAS]

3757-88-8
[Synonyms]

SKL1023
(phenylethynyl)tributyltin
TRIBUTYL(PHENYLETHYNYL)TIN
PHENYLETHYNYLTRI-N-BUTYLTIN
Tributyl(phenylethynyl)tin 95%
tributyl(2-phenylethynyl)Stannane
Tri-n-butyl(phenylethynyl)tin, 95%
PHENYLETHYNYLTRI-N-BUTYLTIN ISO 9001:2015 REACH
[Molecular Formula]

C20H32Sn
[MDL Number]

MFCD00075186
[MOL File]

3757-88-8.mol
[Molecular Weight]

391.18
Chemical PropertiesBack Directory
[density ]

1.116 g/mL at 25 °C(lit.)
[refractive index ]

n20/D 1.532(lit.)
[Fp ]

>230 °F
[storage temp. ]

Storage temp. -20°C
[form ]

liquid
[Specific Gravity]

1.116
[Appearance]

Colorless to light yellow Liquid
[Hydrolytic Sensitivity]

2: reacts with aqueous acid
[InChI]

1S/C8H5.3C4H9.Sn/c1-2-8-6-4-3-5-7-8;3*1-3-4-2;/h3-7H;3*1,3-4H2,2H3;
[InChIKey]

PYMPTRMDPJYTDF-UHFFFAOYSA-N
[SMILES]

CCCC[Sn](CCCC)(CCCC)C#Cc1ccccc1
Safety DataBack Directory
[Symbol(GHS) ]

Skull and Crossbones (GHS06)Health Hazard (GHS08)Environment (GHS09)
GHS06,GHS08,GHS09
[Signal word ]

Danger
[Hazard statements ]

H301-H312-H315-H319-H360FD-H372-H410
[Precautionary statements ]

P202-P273-P280-P301+P310-P302+P352+P312-P305+P351+P338
[Hazard Codes ]

T,N
[Risk Statements ]

21-25-36/38-48/23/25-50/53
[Safety Statements ]

35-36/37/39-45-60-61
[RIDADR ]

UN 2788 6.1/PG 3
[WGK Germany ]

3
[TSCA ]

No
[HazardClass ]

6.1(b)
[PackingGroup ]

III
[Storage Class]

6.1C - Combustible acute toxic Cat.3
toxic compounds or compounds which causing chronic effects
[Hazard Classifications]

Acute Tox. 3 Oral
Acute Tox. 4 Dermal
Aquatic Acute 1
Aquatic Chronic 1
Eye Irrit. 2
Repr. 1B
Skin Irrit. 2
STOT RE 1
Hazard InformationBack Directory
[Uses]

Tributyl(phenylethynyl)tin can be used:
  • As a substrate in the palladium-catalyzed homocoupling of?organostannanes to yield biaryl compounds.
  • To prepare various enynals, which are employed in the synthesis of substituted benzene derivatives catalyzed by nickel.
  • In one of the key synthetic steps for the preparation of β-alkynylcorroles.

Spectrum DetailBack Directory
[Spectrum Detail]

PHENYLETHYNYLTRI-N-BUTYLTIN(3757-88-8)1HNMR
PHENYLETHYNYLTRI-N-BUTYLTIN(3757-88-8)Raman
PHENYLETHYNYLTRI-N-BUTYLTIN(3757-88-8)IR
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