| Identification | Back Directory | [Name]
Allyldicarbonylcyclopentadienyliron | [CAS]
38960-10-0 | [Synonyms]
Allyldicarbonylcyclopentadienyliron
Allyl(cyclopentadienyl)iron(II) dicarbonyl
Dicarbonyl-eta5-cyclopentadienyl(eta1-allyl)iron
(eta1-Allyl)dicarbonyl(eta5-cyclopentadienyl)iron | [Molecular Formula]
C10H4FeO2 | [MOL File]
38960-10-0.mol | [Molecular Weight]
211.99 |
| Hazard Information | Back Directory | [Preparation]
Allyldicarbonylcyclopentadienyliron is prepared under an inert atmosphere by the addition of excess Allyl Chloride to a degassed THF solution of Sodium Dicarbonylcyclopentadienylferrate at 0 °C. The mixture is stirred for 15 min, warmed to room temperature over 1 h, and concentrated in vacuo. The residue is extracted with pentane, filtered, then concentrated in vacuo to give Cp(CO)2Fe(CH2HC=CH2) in 96% crude yield. | [storage]
All manipulations involving Cp(CO)2Fe(CH2HC=CH2) should be carried out under an inert atmosphere. Solvents should be thoroughly dried and degassed. |
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