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39929-21-0

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39929-21-0 Structure

39929-21-0 Structure
IdentificationBack Directory
[Name]

-
[CAS]

39929-21-0
[Synonyms]

2-chlorothiolane:gold
Chloro(tetrahydrothiophene)gold(I), min. 98%
[Molecular Formula]

C4H8AuClS
[MDL Number]

MFCD28411665
[MOL File]

39929-21-0.mol
[Molecular Weight]

319.583
Chemical PropertiesBack Directory
[Melting point ]

>140 °C (decomp)
[storage temp. ]

-20°C, protect from light, stored under nitrogen
[form ]

Powder
[color ]

white to off-white
[Sensitive ]

air sensitive, heat sensitive, light sensitive, store cold
[InChI]

InChI=1S/C4H7ClS.Au/c5-4-2-1-3-6-4;/h4H,1-3H2;
[InChIKey]

XJRWJWUJRQWCBL-UHFFFAOYSA-N
[SMILES]

[Au].ClC1([H])C([H])([H])C([H])([H])C([H])([H])S1
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Corrosion (GHS05)
GHS07,GHS05
[Signal word ]

Danger
[Hazard statements ]

H302-H312-H413-H290-H332-H318-H314
[Precautionary statements ]

P264-P270-P301+P312-P330-P501-P261-P271-P304+P340-P312-P280-P302+P352-P312-P322-P363-P501-P234-P390-P404-P280-P305+P351+P338-P310-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
[WGK Germany ]

WGK 3
[Storage Class]

8A - Combustible corrosive hazardous materials
[Hazard Classifications]

Acute Tox. 4 Dermal
Acute Tox. 4 Inhalation
Acute Tox. 4 Oral
Aquatic Chronic 4
Eye Dam. 1
Skin Corr. 1B
Questions And AnswerBack Directory
[Reaction]

  1. Employed as co-catalyst in Pd-catalyzed alkynylation.
  2. Au-catalyzed phenol synthesis.
    Reactions of 39929-21-0
 
Hazard InformationBack Directory
[Uses]

Au(tht)Cl is a homogenous gold catalyst used for alkynylation, C-H activation, and isomerization.
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