| Identification | Back Directory | [Name]
ANTHRACENE, 9-BROMO-10-(1-NAPHTHALENYL)- | [CAS]
400607-04-7 | [Synonyms]
BA1N
9-BroMo-10-(1-naphthyl)anth
racene
10-broMo-9-(phthalen-1-yl)anthracene
9-Bromo-10-(1-naphthalenyl)anthracene
9-Bromo-10-(naphthalen-1-yl)anthracene
10-BroMo-9-(naphthalene-1-yl)Anthracene
10-(naphthalen-1-yl)anthracen-9-broMine
ANTHRACENE, 9-BROMO-10-(1-NAPHTHALENYL)- | [EINECS(EC#)]
1312995-182-4 | [Molecular Formula]
C24H15Br | [MDL Number]
MFCD11046571 | [MOL File]
400607-04-7.mol | [Molecular Weight]
383.286 |
| Chemical Properties | Back Directory | [Melting point ]
177.0 to 181.0 °C | [Boiling point ]
508.0±19.0 °C(Predicted) | [density ]
1.402±0.06 g/cm3(Predicted) | [storage temp. ]
Sealed in dry,Room Temperature | [solubility ]
soluble in Toluene | [form ]
Solid | [color ]
Pale yellow | [InChI]
InChI=1S/C24H15Br/c25-24-21-13-5-3-11-19(21)23(20-12-4-6-14-22(20)24)18-15-7-9-16-8-1-2-10-17(16)18/h1-15H | [InChIKey]
SYACRXBYRNYMLN-UHFFFAOYSA-N | [SMILES]
C1=C2C(C(C3=C4C(C=CC=C4)=CC=C3)=C3C(=C2Br)C=CC=C3)=CC=C1 |
| Hazard Information | Back Directory | [Chemical Properties]
Off-white powder | [Synthesis]
The general procedure for the synthesis of 9-bromo-10-(1-naphthalenyl)anthracene using 9-(naphthalen-1-yl)anthracene as starting material was as follows: 9-(naphthalen-1-yl)anthracene (88 g, 0.29 mol) was dissolved in dimethylformamide (700 mL) in a 2 L four-necked round-bottomed flask. Subsequently, a solution of N-bromosuccinimide (NBS, 70.7 g, 0.4 mol) in dimethylformamide (200 mL) was added slowly and dropwise. The reaction mixture was stirred at room temperature for 2 hours. Upon completion of the reaction, the reaction mixture was poured into water to precipitate 9-bromo-10-(1-naphthyl)anthracene (108 g, 97.5% yield). | [References]
[1] Journal of Materials Chemistry, 2012, vol. 22, # 1, p. 123 - 129
[2] Patent: US2017/12214, 2017, A1. Location in patent: Paragraph 0166; 0167
[3] Chemical Communications, 2016, vol. 52, # 73, p. 10956 - 10959
[4] Patent: KR2016/90242, 2016, A. Location in patent: Paragraph 0266; 0267; 0268; 0269; 0270; 0271
[5] Patent: KR2017/55704, 2017, A. Location in patent: Paragraph 0111; 0118-0123 |
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