| Identification | Back Directory | [Name]
ethyl 4,4,4-trifluorobut-2-enoate | [CAS]
406-10-0 | [Synonyms]
ethyl 4,4,4-trifluorobut-2-enoate
4,4,4-trifluoro-2-Butenoic acid ethyl ester
2-Butenoic acid, 4,4,4-trifluoro-, ethyl ester | [Molecular Formula]
C6H7F3O2 | [MDL Number]
MFCD00009903 | [MOL File]
406-10-0.mol | [Molecular Weight]
168.11 |
| Chemical Properties | Back Directory | [density ]
1.125 g/mL at 25 °C(lit.) | [refractive index ]
n20/D 1.3601(lit.) | [Fp ]
26°C | [form ]
liquid | [Boiling point ]
114-115°C(lit.) | [InChI]
1S/C6H7F3O2/c1-2-11-5(10)3-4-6(7,8)9/h3-4H,2H2,1H3/b4-3+ | [InChIKey]
ZKRJCMKLCDWROR-ONEGZZNKSA-N | [SMILES]
CCOC(=O)\C=C\C(F)(F)F |
| Hazard Information | Back Directory | [Uses]
Ethyl 4,4,4-trifluorocrotonate was used in the synthesis of (2S,3S)-3-methyl- and (2S,3S)-3-trifluoromethylpyroglutamic acid. It undergoes diastereoselective Michael addition reaction with ethyl crotonate. | [General Description]
The Michael reaction between ethyl 4,4,4-trifluorocrotonate and a Ni(II) complex of the Schiff base of glycine with (S)-o-[N-(N-benzylprolyl)amino]benzophenone was studied. |
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