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406681-09-2

406681-09-2 Structure

406681-09-2 Structure
IdentificationBack Directory
[Name]

(R)-METHYL BOPHOZ(TM)
[CAS]

406681-09-2
[Synonyms]

(s)-methyl bophoz
(S)-METHYL BOPHOZ(TM)
(R)-METHYL BOPHOZ(TM)
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-((R)-2&
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(R)-N-DIPHENYLPHOSPHINO-N-METHYL-[(S)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE
(S)-N-Methyl-N-diphenylphosphino-1-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine
(1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene
Ferrocene,1-(diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)MethylaMino]ethyl]-, (1S)-
(S)-1-[(R)-2-Diphenylphosphinoferrocenyl](N-Methyl)(N-diphenylphosphino)ethylaMine (S)-Me-Bophoz
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine Methyl BoPhoz
(S)-N-Diphenylphosphino-N-methyl-(R)-2-(diphenylphosphino)ferrocenylüethylamine, (S)-Methyl BoPhoz
(S)-N-DIPHENYLPHOSPHINO-N-METHYL-[(R)-2-(DIPHENYLPHOSPHINO)FERROCENYL]ETHYLAMINE, (S)-METHYL BOPHOZ-
Methyl-BoPhoz, (1S)-1-(Diphenylphosphino)-2-[(1S)-1-[(diphenylphosphino)methylamino]ethyl]ferrocene
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (S)-Methyl BoPhoz^t
(S)-N-Diphenylphosphino-N-methyl-[(R)-2-(diphenylphosphino)ferrocenyl]ethylamine, (S)-Methyl BoPhozTM
[Molecular Formula]

C37H35FeNP2 10*
[MDL Number]

MFCD05865220
[MOL File]

406681-09-2.mol
[Molecular Weight]

611.47
Chemical PropertiesBack Directory
[Appearance]

Yellow to orange amorphous solid
[Melting point ]

80-82°C
[form ]

solid
[color ]

yellow
Hazard InformationBack Directory
[Chemical Properties]

Yellow to orange amorphous solid
[Uses]

Methyl-BoPhoz can be used:
  • As an efficient ligand for asymmetric hydrogenation reactions.
  • To synthesize a single enantiomer of cyclopropylalanine via hydrogenation reaction using rhodium catalyst.
  • To prepare chiral phenylalanine derivatives from α-amido cinnamic acids (or esters) using rhodium catalyst.

Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. Ligand used in the rhodium-catalyzed, asymmetric hydrogenation of β-amido-vinylphosphonates.
  2. Ligand used in the rhodium or iridium-catalyzed asymmetric hydrogenation of α,β-unsaturated esters.
Reactions of 406681-09-2
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