| Identification | Back Directory | [Name]
2-IODOBENZENE-1,3-DIOL | [CAS]
41046-67-7 | [Synonyms]
2-Iodoresorcino
2-Iodoresorcinol
2-Iodoresorcinol>
2-iodo-1,3-Benzenediol
2-IODOBENZENE-1,3-DIOL
1,3-Benzenediol, 2-iodo-
1,3-Dihydroxy-2-iodobenzene
2-IODOBENZENE-1,3-DIOL ISO 9001：2015 REACH | [Molecular Formula]
C6H5IO2 | [MDL Number]
MFCD09701440 | [MOL File]
41046-67-7.mol | [Molecular Weight]
236.01 |
| Questions And Answer | Back Directory | [Synthesis]
Sodium bicarbonate (27.9 g, 333 mmol) was added to an aqueous solution (225 mL) of resorcinol (33.0 g, 300 mmol) and iodine (81.5 g, 321 mmol). The solution was cooled to 0°C and stirred. The solution was gradually warmed to ambient temperature over 1 hour. Extraction was performed with diethyl ether, the organic layers were combined, dried over sodium sulfate, filtered, and concentrated under reduced pressure to give a white solid. The solid was ground in chloroform (100 mL) cooled to -10°C. After 30 minutes, the precipitate was filtered and washed with cold chloroform to give the title compound as a white solid (49.0 g, 69%). ¹H NMR (DMSO-d₆) Δδ 6.33 (d, 2H), 6.93 (t, 1H), 10.03 (s, 2H). 
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| Chemical Properties | Back Directory | [Melting point ]
115-119℃ | [Boiling point ]
197.2±20.0 °C(Predicted) | [density ]
2.177±0.06 g/cm3(Predicted) | [solubility ]
Dichloromethane, Ethyl Acetate | [form ]
Solid | [pka]
8.00±0.10(Predicted) | [color ]
Pink | [Sensitive ]
Light Sensitive | [InChI]
InChI=1S/C6H5IO2/c7-6-4(8)2-1-3-5(6)9/h1-3,8-9H | [InChIKey]
BNJXHRMYHDWZKL-UHFFFAOYSA-N | [SMILES]
C1(O)=CC=CC(O)=C1I |
| Hazard Information | Back Directory | [Uses]
2-Iodobenzene-1,3-diol is involved in the facile synthesis of amino acid-derived novel chiral hypervalent iodine(V) reagents. |
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J & K SCIENTIFIC LTD.
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18210857532 18210857532 |
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Alfa Aesar
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Shangchem Co., Ltd.
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