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4112-22-5

4112-22-5 Structure

4112-22-5 Structure
IdentificationBack Directory
[Name]

Chromium, bis(acetato-κO)dioxo-, (T-4)-
[CAS]

4112-22-5
[Synonyms]

Chromium, bis(acetato-κO)dioxo-, (T-4)-
[Molecular Formula]

C4H6CrO6
[MOL File]

4112-22-5.mol
[Molecular Weight]

202.08
Chemical PropertiesBack Directory
[Melting point ]

mp 30.5 °C
[solubility ]

sol CCl4, Ac2O, HOAc; slowly oxidizes many solvents
Hazard InformationBack Directory
[Uses]

(T-4)-bis(acetato-κO)dioxo-Chromium is used as an oxidizing agent for carbon-hydrogen bonds, carbon-carbon double bonds, macrocyclic lactones, and alcohols.
[Preparation]

(T-4)-bis(acetato-κO)dioxo-Chromium is prepared in situ from CrO3 and Ac2O or Ac2O/HOAc. Slow addition of CrO3 to a cooled solution of Ac2O is recommended in order to avoid a highly exothermic reaction.
[Precautions]

(T-4)-bis(acetato-κO)dioxo-Chromium is toxic and should be handled with care and disposed of in conformance with established procedures. This reagent should be handled in a fume hood.
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