ChemicalBook--->CAS DataBase List--->4215-80-9

4215-80-9

4215-80-9 Structure

4215-80-9 Structure
IdentificationBack Directory
[Name]

AMINOTRIPHENYLSILANE
[CAS]

4215-80-9
[Synonyms]

TPSA
TRIPHENYLSILYLAMINE
Triphenylsilanamine
TRIPHENYLAMINOSILANE
AMINOTRIPHENYLSILANE
Triphenylsilylamine 97%
1,1,1-Triphenylsilanamine
1,1,1-TRIPHENYLSILYLAMINE
SilanaMine, 1,1,1-triphenyl-
[amino-di(phenyl)silyl]benzene
[azanyl-di(phenyl)silyl]benzene
Aminotriphenylsilane, TPSA, Triphenylaminosilane
[EINECS(EC#)]

224-147-7
[Molecular Formula]

C18H17NSi
[MDL Number]

MFCD00042816
[MOL File]

4215-80-9.mol
[Molecular Weight]

275.42
Chemical PropertiesBack Directory
[Melting point ]

60-62 °C(lit.)
[Boiling point ]

187-200 °C(Press: 2 Torr)
[density ]

1.10±0.1 g/cm3(Predicted)
[storage temp. ]

−20°C
[solubility ]

Chloroform (Slightly), Methanol (Slightly)
[form ]

Solid
[pka]

6.31±0.70(Predicted)
[color ]

White to Off-White
[Hydrolytic Sensitivity]

7: reacts slowly with moisture/water
[Stability:]

Hygroscopic, Moisture Sensitive
Safety DataBack Directory
[Hazard Codes ]

Xi
[Risk Statements ]

36/37/38
[Safety Statements ]

26
[WGK Germany ]

3
[F ]

10-21
[TSCA ]

No
[HS Code ]

2931900090
Hazard InformationBack Directory
[Uses]

Triphenylsilylamine is used as a reagent to produce 2-Amino-3-hydroxy-indoles with potent in vivo antimalarial activity. Triphenylsilylamine is also used to modify Mo/HZSM-5 catalysts and is predicted to have effects on selectivity in the methane-to-benzene (MTB) reaction.
[Uses]

Triphenylsilylamine may be used in the following studies:
  • Preparation of dimers of the type [Ti(μ-NR)(NMe2)2]2 (R = 1-adamantyl, (t)Bu, SiPh3).
  • Silylation during the pretreatment of fused silica capillary surface to achieve a homogeneous film.
  • Preparation of triphenylsilylsulfinylamine, via reaction with thionylchloride.
  • To investigate the molecular tuning effect of silanation treatment for HZSM-5 crystals.
  • Synthesis of 9-aminopyrido[3′,3′:4,5]pyrrolo[1,2-c]pyrimidine (9-aminosubstituted derivative).
[General Description]

Triphenylsilylamine is a silyl compound.
Spectrum DetailBack Directory
[Spectrum Detail]

AMINOTRIPHENYLSILANE(4215-80-9)1HNMR
AMINOTRIPHENYLSILANE(4215-80-9)Raman
AMINOTRIPHENYLSILANE(4215-80-9)IR
AMINOTRIPHENYLSILANE(4215-80-9)FT-IR
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