| Identification | Back Directory | [Name]
AMINOTRIPHENYLSILANE | [CAS]
4215-80-9 | [Synonyms]
TPSA
TRIPHENYLSILYLAMINE
Triphenylsilanamine
TRIPHENYLAMINOSILANE
AMINOTRIPHENYLSILANE
Triphenylsilylamine 97%
1,1,1-Triphenylsilanamine
1,1,1-TRIPHENYLSILYLAMINE
SilanaMine, 1,1,1-triphenyl-
[amino-di(phenyl)silyl]benzene
[azanyl-di(phenyl)silyl]benzene
Aminotriphenylsilane, TPSA, Triphenylaminosilane | [EINECS(EC#)]
224-147-7 | [Molecular Formula]
C18H17NSi | [MDL Number]
MFCD00042816 | [MOL File]
4215-80-9.mol | [Molecular Weight]
275.42 |
| Chemical Properties | Back Directory | [Melting point ]
60-62 °C(lit.) | [Boiling point ]
187-200 °C(Press: 2 Torr) | [density ]
1.10±0.1 g/cm3(Predicted) | [storage temp. ]
−20°C | [solubility ]
Chloroform (Slightly), Methanol (Slightly) | [form ]
Solid | [pka]
6.31±0.70(Predicted) | [color ]
White to Off-White | [Hydrolytic Sensitivity]
7: reacts slowly with moisture/water | [Stability:]
Hygroscopic, Moisture Sensitive |
| Hazard Information | Back Directory | [Uses]
Triphenylsilylamine is used as a reagent to produce 2-Amino-3-hydroxy-indoles with potent in vivo antimalarial activity. Triphenylsilylamine is also used to modify Mo/HZSM-5 catalysts and is predicted to have effects on selectivity in the methane-to-benzene (MTB) reaction. | [Uses]
Triphenylsilylamine may be used in the following studies:
- Preparation of dimers of the type [Ti(μ-NR)(NMe2)2]2 (R = 1-adamantyl, (t)Bu, SiPh3).
- Silylation during the pretreatment of fused silica capillary surface to achieve a homogeneous film.
- Preparation of triphenylsilylsulfinylamine, via reaction with thionylchloride.
- To investigate the molecular tuning effect of silanation treatment for HZSM-5 crystals.
- Synthesis of 9-aminopyrido[3′,3′:4,5]pyrrolo[1,2-c]pyrimidine (9-aminosubstituted derivative).
| [General Description]
Triphenylsilylamine is a silyl compound. |
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