ChemicalBook--->CAS DataBase List--->42532-60-5

42532-60-5

42532-60-5 Structure

42532-60-5 Structure
IdentificationBack Directory
[Name]

Perfluoroisobutyronitrile
[CAS]

42532-60-5
[Synonyms]

Perfluoroisobutyronitrile
Propanenitrile, 2,3,3,3-tetrafluoro-2-(trifluoromethyl)-
[EINECS(EC#)]

806-451-7
[Molecular Formula]

C4F7N
[MDL Number]

MFCD18641876
[MOL File]

42532-60-5.mol
[Molecular Weight]

195.04
Chemical PropertiesBack Directory
[Boiling point ]

26.1±40.0 °C(Predicted)
[density ]

1.545±0.06 g/cm3(Predicted)
[vapor pressure ]

296.509kPa at 25℃
[Henry's Law Constant]

1.6×10-8 mol/(m3Pa) at 25℃, Ebert et al. (2023)
[InChI]

InChI=1S/C4F7N/c5-2(1-12,3(6,7)8)4(9,10)11
[InChIKey]

AASDJASZOZGYMM-UHFFFAOYSA-N
[SMILES]

C(#N)C(F)(C(F)(F)F)C(F)(F)F
[LogP]

1.7-4.3 at 23.9-24℃
[EPA Substance Registry System]

Propanenitrile, 2,3,3,3-tetrafluoro-2-(trifluoromethyl)- (42532-60-5)
Safety DataBack Directory
[Symbol(GHS) ]

Exclamation Mark (GHS07)Gas Cylinder (GHS04)
GHS07,GHS04
[Signal word ]

Warning
[Hazard statements ]

H332-H280
[Precautionary statements ]

P410+P403-P261-P271-P304+P340-P312
[TSCA ]

TSCA listed
[REACH Registrations]

Active
Hazard InformationBack Directory
[Uses]

Perfluoroisobutyronitrile is promoted as an alternative to sulfur hexafluoride (SF6) for interruption and insulation applications, it is also used as a dielectric additive.
[Synthesis Reference(s)]

[1]G. C. Michael, M. F. Richard, J. B. Michael. Fluorinated nitriles as dielectric gases: USA, 0083979[P]. 2015-03-26.
[Synthesis]

In 2015, Michael et al.[1] obtained perfluorinated isobutylamide by reacting perfluorinated isobutylamide with ammonia gas, then perfluorinated isobutylamide underwent dehydration reaction under the action of pyridine and trifluoroacetic anhydride, and perfluorinated isobutylnitrile with 75% yield (Fig. 6). The method has mild conditions and no highly toxic and expensive reagents, so it has the prospect of industrial production. Dehydration of perfluoroisobutylamide
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