443965-10-4

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443965-10-4 Structure

Identification	Back Directory
[Name] (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
[CAS] 443965-10-4
[Synonyms] (R)-SIPHOS (S)-SIPHOS N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE N-Dimethyl-[(S)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98% N-DIMETHYL-[(S)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (S)-SIPHOS (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE N,N-Dimethylphosphoramidousacid (1S)-(2,2',3,3'-tetrahydro-1,1'-spirobi[1H-indene]-7,7'-diyl) ester (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (11aS)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1 -de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,99%e.e. Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine,10,11,12,13-tetrahydro-N,N-dimethyl-, (11aS)- (9CI) (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(S)-SIPHOS (11aS)-(-)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(S)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite
[Molecular Formula] C19H20NO2P
[MDL Number] MFCD08459340
[MOL File] 443965-10-4.mol
[Molecular Weight] 325.34

Chemical Properties	Back Directory
[Melting point ] 95-96°C
[alpha ] -502° (c 0.5, CH2Cl2)
[storage temp. ] -20°C
[form ] solid
[color ] white
[Sensitive ] moisture sensitive

Hazard Information	Back Directory
[Chemical Properties] White to light yellow powder

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H335-H319-H315
[Precautionary statements ] P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
[HS Code ] 29252900

Raw materials And Preparation Products	Back Directory
[Raw materials] Toluene-->(S)-1,1'-SPIROBIINDANE-7,7'-DIOL-->Hexamethylphosphorous triamide

[Reaction]

Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.

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