| Identification | Back Directory | [Name]
(S)-(-)-1,1'-BINAPHTHYL-2,2'-DIAMINE | [CAS]
4488-22-6 | [Synonyms]
BINAM
S(-)-DABN
R(+)-DABN
1,1-BINAPHY1-2,2'-DIAMINE
1,1'-Bi(2-naphthalenamine)
1,1'-Bi[2-naphthalenamine]
1,1'-Bi[naphthalene-2-amine]
1,1'-Bi(naphthalene-2-amine)
1,1'-BINAPHTHYL-2,2'-DIAMINE
(±)-1,1'-Bi(2-naphthylamine),
2,2-DIAMINO-1,1'-BINAPHTHALENE
1-(1-Naphtyl)naphthalen-2-amine
1,1'-Binaphthyl-2,2'-diamine 96%
(+/-)-2,2'-Diamino-1,1'-binaphthyl
(S)-(-)-2,2'-DIAMINO-1,1'-BINAPHTHYL
S(-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
R(+)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
(R)-(+)-2,2'-DIAMINO-1,1'-BINAPHTHYL
RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL
(+/-)-1,1'-BINAPHTHALENE-2,2'-DIAMINE
(+/-)-2,2'-DIAMINO-1,1'-BINAPHTHALENE
(±)-2,2'-Diamino-1,1'-binaphthalene,98%
racemic-2,2'-Diamino-1,1'-binaphthyl,min.96%
RACEMIC-2,2'-DIAMINO-1,1'-BINAPHTHYL, MIN. 96% | [Molecular Formula]
C20H16N2 | [MDL Number]
MFCD00145204 | [MOL File]
4488-22-6.mol | [Molecular Weight]
284.35 |
| Chemical Properties | Back Directory | [Appearance]
off-white to beige-pink powder | [Melting point ]
242-244 °C(lit.)
| [Boiling point ]
416.85°C (rough estimate) | [density ]
1.249 | [refractive index ]
1.6450 (estimate) | [storage temp. ]
Keep in dark place,Sealed in dry,Room Temperature | [form ]
powder to crystal | [pka]
3.79±0.10(Predicted) | [color ]
slightly beige
| [Optical Rotation]
-0.3137°(C=1.0043g/100ml DCM) | [Water Solubility ]
Insoluble in water | [λmax]
355nm(neat)(lit.) | [InChI]
InChI=1S/C20H16N2/c21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22/h1-12H,21-22H2 | [InChIKey]
DDAPSNKEOHDLKB-UHFFFAOYSA-N | [SMILES]
C1(C2=C3C(C=CC=C3)=CC=C2N)=C2C(C=CC=C2)=CC=C1N |
| Hazard Information | Back Directory | [Chemical Properties]
off-white to beige-pink powder | [Uses]
Novel axially chiral Rh N-heterocyclic carbene complexes were prepared from axially dissymmetric 1,1?-binaphthalenyl-2,2?-diamine and applied in the Rh-catalyzed enantioselective hydrosilylation of methyl ketones. The enantioselective direct aldol reaction, organocatalyzed by recoverable BINAM- prolinamide derivatives can be highly accelerated by a catalytic amount of a carboxylic acid without a detrimental of the obtained enantioselectivities. | [Safety Profile]
Questionable carcinogen withexperimental tumorigenic data. When heated todecomposition it emits toxic fumes of NOx. |
|
| Company Name: |
J & K SCIENTIFIC LTD.
|
| Telephone: |
18210857532 18210857532 |
| Website: |
https://www.jkchemical.com |
| Company Name: |
Alfa Aesar
|
| Telephone: |
400-6106006 |
| Website: |
http://chemicals.thermofisher.cn |
| Company Name: |
Energy Chemical
|
| Telephone: |
400-0056266 |
| Website: |
www.energy-chemical.com |
|