| Identification | Back Directory | [Name]
4-METHOXY-3-BUTEN-2-ONE | [CAS]
4652-27-1 | [Synonyms]
NSC 66263
Methoxy-3-buten
4-METHOXY-3-BUTEN-2-ONE
4-methoxybut-3-en-2-one
1-Methoxy-1-buten-3-one
(E)-4-methoxybut-3-en-2-one
4-Methoxy-3-buten-2-one ,95%
2-Methoxyvinyl methyl ketone
TRANS-1-METHOXY-1-BUTEN-3-ONE
TRANS-4-METHOXY-3-BUTEN-2-ONE
3-buten-2-one, 4-methoxy-, (3Z)-
4-Methoxy-3-buten-2-one, 90%,tech
4-Methoxy-3-buten-2-one, tech., 90% | [EINECS(EC#)]
257-364-0 | [Molecular Formula]
C5H8O2 | [MDL Number]
MFCD00008778 | [MOL File]
4652-27-1.mol | [Molecular Weight]
100.12 |
| Chemical Properties | Back Directory | [Appearance]
clear yellow liquid | [Boiling point ]
200 °C(lit.)
| [density ]
0.982 g/mL at 25 °C(lit.)
| [refractive index ]
n20/D 1.468(lit.)
| [Fp ]
146 °F
| [storage temp. ]
2-8°C
| [solubility ]
Miscible with tetrahydrofuran, ether, acetonitrile and benzene. | [form ]
Liquid | [color ]
Clear yellow | [BRN ]
1741053 | [InChI]
InChI=1S/C5H8O2/c1-5(6)3-4-7-2/h3-4H,1-2H3 | [InChIKey]
VLLHEPHWWIDUSS-UHFFFAOYSA-N | [SMILES]
CC(=O)C=COC |
| Hazard Information | Back Directory | [Chemical Properties]
clear yellow liquid | [Uses]
4-Methoxy-3-buten-2-one is an important precursor for the synthesis of 1-methoxy-3-trimethylsilyloxy-1,3-butadiene and the Danishefsky diene and its equivalent. It is widely used as a reactant in the synthesis of hydroisoquinoline derivatives. It is employed as an intermediate for the synthesis of manzamine. | [Toxics Screening Level]
Due to a lack of available toxicity information the ITSL is being set at the default value of 0.1 μg/m3 with annual averaging, based on R232(1)(i). |
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