ChemicalBook--->CAS DataBase List--->4680-24-4

4680-24-4

4680-24-4 Structure

4680-24-4 Structure
IdentificationBack Directory
[Name]

(+)-CIS-LIMONENE 1,2-EPOXIDE
[CAS]

4680-24-4
[Synonyms]

LMO
cis-limonene oxide
cis-Limonene oxyde
(Z)-Limonene oxide
Limonene oxide, cis-
Limonene, epoxy, cis
cis-1,2-Limonene epoxide
(+)-CIS-LIMONENE 1,2-EPOXIDE
(1R,4R)-1,2-EPOXY-P-MENTH-8-ENE
(+)-CIS-LIMONENE 1,2-EPOXIDE 97+%
(4R)-limonene 1beta,2beta-epoxide
(1R,2S,4R)-1,2-Epoxy-p-mentha-8-ene
(1S,2R,4S)-1,2-Epoxy-p-mentha-8-ene
(+)-CIS-P-MENTHA-1,8-DIENE 1,2-EPOXIDE
(1R)-1,2β-Epoxy-1α-methyl-4α-(1-methylethenyl)cyclohexane
(1R,2S,4R)-4-ISOPROPENYL-1-METHYL-1-CYCLOHEXENE 1,2-EPOXIDE
(1R,4R,6S)-1-Methyl-4-isopropenyl-7-oxabicyclo[4.1.0]heptane
Benzenesulfonylchloride,4-methoxy-2-methyl-5-(5-methylethyl)-
(1S,6α)-1-Methyl-4α-(1-methylvinyl)-7-oxabicyclo[4.1.0]heptane
(1R,4R,6S)-1-Methyl-4-(1-methylethenyl)-7-oxabicyclo[4.1.0]heptane
7-Oxabicyclo[4.1.0]heptane, 1-methyl-4-(1-methylethenyl)-, (1R,4R,6S)-
7-Oxabicyclo[4.1.0]heptane,1-methyl-4-(1-methylethenyl)-,(1R,4R,6S)-(9CI)
(+)-cis-p-Mentha-1,8-diene 1,2-epoxide, (1R,4R)-1,2-Epoxy-p-menth-8-ene, (1R,2S,4R)-4-Isopropenyl-1-methyl-1-cyclohexene 1,2-epoxide
[Molecular Formula]

C10H16O
[MDL Number]

MFCD00142328
[MOL File]

4680-24-4.mol
[Molecular Weight]

152.23
Chemical PropertiesBack Directory
[Melting point ]

>1000 °C
[Boiling point ]

113-114 °C(Press: 50 Torr)
[density ]

0.931 g/mL at 20 °C(lit.)
[refractive index ]

n20/D 1.466
[Fp ]

65 °C
[storage temp. ]

2-8°C
[form ]

liquid
[InChI]

1S/C10H16O/c1-7(2)8-4-5-10(3)9(6-8)11-10/h8-9H,1,4-6H2,2-3H3/t8-,9+,10-/m0/s1
[InChIKey]

CCEFMUBVSUDRLG-AEJSXWLSSA-N
[SMILES]

O1[C@@]2([C@H]1C[C@H](CC2)C(=C)C)C
[LogP]

3.200 (est)
Safety DataBack Directory
[Safety Statements ]

23-24/25
[WGK Germany ]

3
[F ]

10-21
[Storage Class]

10 - Combustible liquids
Hazard InformationBack Directory
[Uses]

cis-(+)-Limonene oxide can be used as:
  • A monomer to prepare poly(limonene)carbonate by Al(III) catalyzed coupling reaction with CO2.
  • A reactant to prepare trans-diaxial diol via diastereoselective ring-opening reaction using molybdenum complex catalyst.
  • A reactant to synthesize trans-dihydrocarvone via isomerization reaction in the presence of silica-supported tungstophosphoric acid as a catalyst and dialkylcarbonate as a green solvent.

', 'cis-(+)-Limonene oxide is a valuable chiral terpene oxide building block.
[Definition]

ChEBI: (4R)-limonene 1beta,2beta-epoxide is a (4R)-limonene 1,2-epoxide.
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