| Identification | Back Directory | [Name]
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE | [CAS]
470480-32-1 | [Synonyms]
(S,S,R,R)-TANGPHOS
(S,S',R,R')-TANGPHOS
(1S,1S',2R,2R')-1,1'-DI-TERT-BUTYL-(2,2')-DIPHOSPHOLANE
(1S,1S',2R,2R')-(+)-1,1'-DI-T-BUTYL-[2,2']-DIPHOSPHOLANE
(2R)-1-tert-butyl-2-[(2R)-1-tert-butylphospholan-2-yl]phospholane
2,2'-Biphospholane, 1,1'-bis(1,1-dimethylethyl)-, (1S,1'S,2R,2'R)-
(1S,1S'',2R,2R'')-(+)-1,1''-DI-T-BUTYL-[2,2'']-DIPHOSPHOLANE (S,S,R,R)-TANGPHOS
(1S,1'S,2R,2'R)-(+)-1,1'-Di-t-butyl-[2,2']-diphospholane,min.95%(S,S,R,R)-TANGPHOS | [Molecular Formula]
C16H32P2 | [MDL Number]
MFCD06658118 | [MOL File]
470480-32-1.mol | [Molecular Weight]
286.37 |
| Chemical Properties | Back Directory | [Melting point ]
60-65 °C | [Boiling point ]
353.6±12.0 °C(Predicted) | [InChI]
1S/C16H32P2/c1-15(2,3)17-11-7-9-13(17)14-10-8-12-18(14)16(4,5)6/h13-14H,7-12H2,1-6H3/t13-,14-,17+,18+/m1/s1 | [InChIKey]
SJNUZTRUIDRSJK-KNCCTNLNSA-N | [SMILES]
CC(C)(C)P1CCC[C@@H]1[C@H]2CCCP2C(C)(C)C |
| Hazard Information | Back Directory | [Uses]
Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation
Catalytic ligand used in:
- Preparation of α-borono-substituted alkylarenes by asymmetric hydroboration of styrenes catalyzed by copper(I)
- Enantioselective synthesis of spiroindane di-Me acetic acid via hydrogenation of spiroindane di-Me acetic acid catalyzed by Ru(II)
- Asymmetric γ-addition of thiols to allenoates
- Rhodium-catalyzed intermolecular enantioselective hydroacylation of alkynes to give alpha- and beta-substituted unsaturated ketones by kinetic resolution
- Stereoselective preparation of β-amino nitriles via rhodium-catalyzed asymmetric hydrogenation of amino acrylonitriles
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