472-66-2

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472-66-2 Structure

Identification	Back Directory
[Name] 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE
[CAS] 472-66-2
[Synonyms] FEMA 3474 B-HOMOCYCLOCITRAL β-Homocyclocitral beta-Homocyclocitral homo cyclocitral, beta Ethyl ring high citral 2 6 6-TRIMETHYL-1-CYCLOHEXENE-1-ACET- & 2,6,6-trimethyl-1-cyclohexene-1-acetaldehyd 2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE 2-(2,6,6-trimethylcyclohexen-1-yl)acetaldehyde 1-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl- (2,6,6-Trimethyl-1-cyclohexen-1-yl)acetaldehyde 2-(2,6,6-triMethylcyclohex-1-en-1-yl)acetaldehyde 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDE HYDE, TECH., 80% 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde,β-Homocyclocitral 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde technical grade, 80%
[EINECS(EC#)] 207-454-0
[Molecular Formula] C11H18O
[MDL Number] MFCD00012057
[MOL File] 472-66-2.mol
[Molecular Weight] 166.26

Chemical Properties	Back Directory
[Boiling point ] 58-59 °C/0.4 mmHg (lit.)
[density ] 0.941 g/mL at 25 °C (lit.)
[FEMA ] 3474 \| 2,6,6-TRIMETHYL-1-CYCLOHEXEN-1-ACETALDEHYDE
[refractive index ] n20/D 1.485(lit.)
[Fp ] 191 °F
[storage temp. ] 2-8°C
[form ] liquid
[Odor] at 10.00 % in dipropylene glycol. camphoreous cooling woody medicinal oily berry orris soapy
[biological source] synthetic
[Odor Type] camphoreous
[JECFA Number] 978
[LogP] 3.94
[EPA Substance Registry System] 1-Cyclohexene-1-acetaldehyde, 2,6,6-trimethyl- (472-66-2)

Hazard Information	Back Directory
[Uses] 2,6,6-Trimethyl-1-cyclohexene-1-acetaldehyde can be used as a starting material to prepare: (±)-Aeginetolide by oxidation in the presence of meta-chloroperoxybenzoic acid (m-CPBA). (±)-Dihydroactinidiolide (a C₁₁-terpenic lactone) via dehydration of key intermediate aeginetolide. It can also be used as a key intermediate to synthesize drimane-related sesquiterpenes and substituted retinoic acid analogs.
[Definition] ChEBI: 2,6,6-Trimethyl-1-cyclohexen-1-acetaldehyde is an aldehyde.
[Taste threshold values] Taste characteristics at 15 ppm: cooling, woody, oily, soapy, citrus with a berry, orris-like nuance.

Spectrum Detail	Back Directory
[Spectrum Detail] 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE(472-66-2)MS 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE(472-66-2)¹HNMR 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE(472-66-2)¹³CNMR 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE(472-66-2)IR1 2,6,6-TRIMETHYL-1-CYCLOHEXENE-1-ACETALDEHYDE(472-66-2)Raman

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