| Identification | Back Directory | [Name]
5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol | [CAS]
4850-04-8 | [Synonyms]
Nudaurine
Amurinol I
5,6,8,14-Tetradehydro-6-methoxy-17-methyl-2,3-[methylenebisoxy]morphinan-7β-ol
Morphinan-7-ol, 5,6,8,14-tetradehydro-6-methoxy-17-methyl-2,3-[methylenebis(oxy)]-, (7β)- (9CI) | [Molecular Formula]
C19H21NO4 | [MOL File]
4850-04-8.mol | [Molecular Weight]
327.37 |
| Hazard Information | Back Directory | [Description]
A morphine type alkaloid, this base is a minor constituent of the seeds of
Papaver nudicaule var. amurense. It forms clusters of colourless crystals from
Me2CO and has [α] 22
D - 52° (c 1.0, CHCI3). The salts are crystalline and include
the hydriodide, m.p. 198°C (dec.); perchlorate, m.p. 188°C (dec.) and the
picrate, m.p. 150°C (dec.). The structure given above has been determined on the
basis of the infrared, NMR and mass spectra. | [References]
Boit, Flentje., Naturwiss., 47,180 (1960)
Flentje, Dopke, Jeffs., ibid, 52,259 (1965)
Dopke, Flentje, Jeffs., Tetrahedron, 24,4459 (1968)
Absolute configuration:
Barton et ai., Chern. Ber., 100,2457 (1967)
Circular dichroism:
Snatzke, Wollenberg.,!. Chern. Soc., C, 1581 (1966) |
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