ChemicalBook--->CAS DataBase List--->489-86-1

489-86-1

489-86-1 Structure

489-86-1 Structure
IdentificationBack Directory
[Name]

(-)-GUAIOL
[CAS]

489-86-1
[Synonyms]

Gualol
GUAIOL
Champaeol
Nsc 19941
Champacol
GUAIOL(RG)
(-)-GUAIOL
(?)-Guaiol
Natural Guaiol
(-)-Guaiol 97%
Guaiac alcohol
Champaca camphor
Einecs 207-702-8
Guai-1(5)-en-11-ol
L-rel-Guai-1(5)-en-11-ol
5alpha,8alpha)]-s-(3alph
Guai-1(5)-en-11-ol (8ci)
(-)-GUAJOL, TERPENE STANDARD
(-)-Guaiol@100 μg/mL in Methanol
guaiol,guaiacalcohol,(-)-guaiol,champacacamphor,champacol
2-(3,8-Dimethyl-1,2,3,4,5,6,7,8-octahydro-5-azulenyl)-2-propanol
2-(3,8-dimethyl-1,2,3,4,5,6,7,8-octahydro-azulen-5-yl)-propan-2-ol
1,2,3,4,5,6,7,8-Octahydro-α,α,1β,4β-tetramethylazulene-7β-methanol
(3r,6s,10s)-6,10,α,α-tetramethylbicyclo[5.3.0]dec-1(7)-ene-3-methanol
(3S)-1,2,3,4,5,6,7,8-Octahydro-α,α,3α,8α-tetramethyl-5α-azulenemethanol
1,2,3,4,5,6,7,8-octahydro-alpha,alpha,3,8-tetramethyl-5-azulenemethano[3
2-((3S,8S)-1,2,3,4,5,6,7,8-octahydro-3,8-dimethylazulen-5-yl)propan-2-ol
(3S,5S,8S)-1,2,3,4,5,6,7,8-Octahydro-α,α,3,8-tetramethyl-5-azulenemethanol
2-[(3r,5s,8r)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl]propan-2-ol
(3R,6S,10S)-6,10,ALPHA,ALPHA-TETRAMETHYLBICYCLO[5.3.0]DEC-1(7)-ENE-3-METHANOL
5-Azulenemethanol, 1,2,3,4,5,6,7,8-octahydro-α,α,3,8-tetramethyl-, (3S,5R,8S)-
2-[[(3S,5R,8S)-3,8-Dimethyl-1,2,3,4,5,6,7,8-octahydroazulene]-5-yl]-2-propanol
5-Azulenemethanol, 1,2,3,4,5,6,7,8-octahydro-alpha,alpha,3,8-tetramethyl-, (3S,5R,8S)-
5-Azulenemethanol, 1,2,3,4,5,6,7,8-octahydro-alpha,alpha,3,8-tetramethyl-, [3S-(3alpha,5alpha,8alpha)]-
[3S-(3.alpha.,5.alpha.,8.alpha.)]-1,2,3,4,5,6,7,8-octahydro-.alpha.,.alpha.-3,8-tetramethyl-5-azulenemethanol
1,2,3,4,5,6,7,8-octahydro-.alpha.,.alpha.-3,8-tetramethyl-,[3S-(3.alpha.,5.alpha.,8.alpha.)]-5-Azulenemethanol
[EINECS(EC#)]

207-702-8
[Molecular Formula]

C15H26O
[MDL Number]

MFCD00043336
[MOL File]

489-86-1.mol
[Molecular Weight]

222.37
Chemical PropertiesBack Directory
[Definition]

A bicyclic sesquiterpene alcohol found in guaiac wood oil.
[Appearance]

Crystalline solid. Insoluble in water; soluble in alcohol.
[Melting point ]

91-93 °C(lit.)
[alpha ]

D20 -30° (c = 4 in alc)
[Boiling point ]

132-136℃
[density ]

0.9714 g/cm3 (20℃)
[refractive index ]

1.5100 (589.3 nm 20℃)
[storage temp. ]

2-8°C
[solubility ]

Chloroform (Slightly), Dichloromethane (Sparingly), Ethanol (Slightly), Methanol
[form ]

Solid
[pka]

15.11±0.29(Predicted)
[color ]

White to Off-White
[Odor]

at 100.00 %. mild guaiacwood tea rose
[Odor Type]

woody
[Optical Rotation]

[α]20/D 28°, c = 4 in ethanol
[Merck ]

13,4572
[BRN ]

2047993
[Major Application]

food and beverages
[Cosmetics Ingredients Functions]

PERFUMING
[InChI]

1S/C15H26O/c1-10-5-7-12(15(3,4)16)9-14-11(2)6-8-13(10)14/h10-12,16H,5-9H2,1-4H3/t10-,11-,12+/m0/s1
[InChIKey]

TWVJWDMOZJXUID-SDDRHHMPSA-N
[SMILES]

C[C@H]1CC[C@H](CC2=C1CC[C@@H]2C)C(C)(C)O
[LogP]

4.782 (est)
[EPA Substance Registry System]

5-Azulenemethanol, 1,2,3,4,5,6,7,8-octahydro-.alpha.,.alpha.,3,8-tetramethyl-, (3S,5R,8S)- (489-86-1)
Hazard InformationBack Directory
[Chemical Properties]

Crystalline solid. Insoluble in water; soluble in alcohol.
[Uses]

Guaiol is a component of guaiac wood oil, terpenol also found in cannabis.
[Production Methods]

(-)-Guaiol can be produced by extraction from Guaiacwood oil with a volatile solvent, usually Acetone, Ethanol or Ethylether.
It can also be isolated from the wood of certain Australian members of the family Taxodiaceae, particularly the so-called "Murray River Pine".
[General Description]

(-)-Guaiol is a sesquiterpene alcohol which has guaiane skeleton. It naturally occurs in essential oils extracted from Salvia lanigera and Helitta ongifoliata and has antibacterial activity.
[storage]

Store at -20°C
Safety DataBack Directory
[Safety Statements ]

22-24/25
[WGK Germany ]

3
[TSCA ]

TSCA listed
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Aroma]

Deteriorates when exposed to air, becomes semi-liquid, darkens in color and changes odor. Mild, rather sweet and very tenacious balsamic-woody odor with an almost floral undertone and a pepperiness which seem to be apparent only in impure material (possibly traces of hydrocarbons).
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