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490023-37-5

490023-37-5 Structure

490023-37-5 Structure
IdentificationBack Directory
[Name]

(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
[CAS]

490023-37-5
[Synonyms]

3,4-a′]dinaphthalen-4-yl)MethylaMine
(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCL&
3,4-a']dinaphthalen-4-yl)methylamine 97%
3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine,99%
3,4-a']dinaphthalen-4-yl)benzyl(methyl)amine, 99%
(S)-(+)-Benzyl(3,5-dioxa-4-phospha-cyclohepta[2,1-a
N-Benzyl-N-methyldinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)
(11bS)-N-Methyl-N-(phenylmethyl)-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine
(S)-(+)-BENZYL(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)METHYLAMINE
(S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BENZYL(METHYL)AMINE
[Molecular Formula]

C28H22NO2P
[MDL Number]

MFCD04117686
[MOL File]

490023-37-5.mol
[Molecular Weight]

435.45
Chemical PropertiesBack Directory
[Melting point ]

155-159 °C
[alpha ]

+356° (c 0.32, CHCl3)
[form ]

Powder
[color ]

white
[Sensitive ]

moisture sensitive
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H335-H319-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[Risk Statements ]

36/37/38
[Safety Statements ]

26-36/37/39
[WGK Germany ]

3
Questions And AnswerBack Directory
[Reaction]

  1. The ligand has been used in Ir-catalyzed asymmetric hydrogenation of substituted benzophenone N-H imines.
  2. The ligand has been used in the rhodium-catalyzed enantioselective hydrogenation of (E)-N-acylated dehydro-β-aminoacid esters.
Reactions of 490023-37-5
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