| Hazard Information | Back Directory | [Uses]
1-(Trimethylsilyl)vinylmagnesium
Bromide–Copper(I) Iodide reacts with epoxides to give homoallylic alcohols useful for the
synthesis of α-methylenebutyrolactones; can function as a synthon for epoxides; adds to D-glyceraldehyde acetonide to give
epoxy alcohols and D-threose derivatives. It takes part in the reactions of α-Methylenebutyrolactone Synthesis, Addition to D-Glyceraldehyde Acetonide: Preparation
of Epoxy Alcohols and D-Threose Derivatives, etc. | [Preparation]
1-(Trimethylsilyl)vinylmagnesium Bromide-Copper(I) Iodide is prepared in situ under anhydrous conditions by reacting 1-(trimethylsilyl)vinylmagnesium bromide (1)
with Copper(I) Iodide (2) in various molar ratios. |
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