| Identification | Back Directory | [Name]
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][ | [CAS]
500103-26-4 | [Synonyms]
N N-BIS-[(R)-1-PHENYLETHYL]DIBENZO[D F][
N,N-bis[(1S)-1-phenylethyl]-Dibenzo[d,f][1,3,2]dioxaphosphepin-6-aMine
Dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine, N,N-bis[(1R)-1-phenylethyl]-
N,N-Bis[(1R)-(+)-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine,97%
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine >=99.0%
N,N-Bis[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosp
hepin-6-amine,99%e.e.
BIPOL-A1(R), (R,R)-N-(5,7-Diox-6-phosphadibenzo[a,c]cyclohepten-6-yl)bis(1-phenylethyl)amine, O,Oμ-(2,2μ-Biphenyldiyl) N,N-bis[(R)-1-phenylethyl]phosphoramidite | [Molecular Formula]
C28H26NO2P | [MDL Number]
MFCD08277032 | [MOL File]
500103-26-4.mol | [Molecular Weight]
439.49 |
| Chemical Properties | Back Directory | [Melting point ]
99-102 °C | [Boiling point ]
578.4±53.0 °C(Predicted) | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Powder | [pka]
-0.31±0.20(Predicted) | [color ]
white | [Sensitive ]
moisture sensitive | [InChI]
1S/C28H26NO2P/c1-21(23-13-5-3-6-14-23)29(22(2)24-15-7-4-8-16-24)32-30-27-19-11-9-17-25(27)26-18-10-12-20-28(26)31-32/h3-22H,1-2H3 | [InChIKey]
JISGHECLGYELKD-UHFFFAOYSA-N | [SMILES]
C[C@@H](N([C@H](C)c1ccccc1)P2Oc3ccccc3-c4ccccc4O2)c5ccccc5 |
| Hazard Information | Back Directory | [Uses]
N,N-Bis-[(R)-1-phenylethyl]dibenzo[d,f][1,3,2]dioxaphosphepin-6-amine can be used:
- In the asymmetric hydrovinylation of 1,3-diene.
- In the 1,4-asymmetric conjugate addition of 3-substituted cyclohexenones catalyzed by copper.
| [reaction suitability]
reaction type: click chemistry |
|
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