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501-02-0

501-02-0 Structure

501-02-0 Structure
IdentificationBack Directory
[Name]

(2R,6R)-2-methyl-6-prop-1-enyl-piperidine
[CAS]

501-02-0
[Synonyms]

Pinidine
(-)-Pinidine
2α-Methyl-6α-[(E)-1-propenyl]piperidine
(2R,6R)-2-methyl-6-prop-1-enyl-piperidine
(2R)-2-Methyl-6α-[(E)-1-propenyl]piperidine
[Molecular Formula]

C9H17N
[MOL File]

501-02-0.mol
[Molecular Weight]

139.24
Chemical PropertiesBack Directory
[Boiling point ]

176-7oC/751mm
Hazard InformationBack Directory
[Description]

A piperidine alkaloid isolated from Pinus jeffreyi, P. sabiniana Doug!., and P. torreyana, this base is a colourless liquid which is laevorotatory with [Ql~~9 - 10.5° and [Ql~j5 - 23.4° (c 1.88, EtOH). It yields a crystalline hydrochloride as colourless needles from EtOH-AcOEt, m.p. 244-6°C and a methiodide, m.p. 214-8°C. The structure has been determined by spectroscopic methods as 2-methyl-6-( trans-2-propeny I)-piperidine.
[Definition]

ChEBI: Pinidine is a piperidine alkaloid.
[References]

Tallent, Stromberg, Horning.,J. Arner. Chern. Soc., 77,6361 (1955)
Tallent, Horning., ibid, 78,4467 (1956)
Hill, Chan, Joule., Tetrahedron, 21,147 (1965)
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