| Identification | Back Directory | [Name]
Grela 2nd Generation | [CAS]
502964-52-5 | [Synonyms]
nitro-Grela
Ruthenium, [1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro[[2-(1-methylethoxy-κO)-5-n
[1,3-bis (2,4,6-trimethylphenyl) -2- imidazolidinylidene] (2-isopropoxy-5-nitrophenyl methylene) ruthenium dichloride
[1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)]-(2-i-propoxy-5-nitrobenzylidene)ruthenium(II) dichloride nitro-Grela
RutheniuM, [1,3-bis(2,4,6-triMethylphenyl)-2-iMidazolidinylidene]dichloro[[2-(1-Methylethoxy-κO)-5-nitrophenyl]Methylene-κC]-, (SP-5-41)- | [Molecular Formula]
C31H37Cl2N3O3Ru | [MDL Number]
MFCD28411645 | [MOL File]
502964-52-5.mol | [Molecular Weight]
670.62 |
| Chemical Properties | Back Directory | [Melting point ]
>300 °C | [storage temp. ]
2-8°C | [form ]
Powder | [color ]
green | [InChIKey]
WJQJERDWEICOQD-UHFFFAOYSA-L | [SMILES]
[Cl-][Ru+6]1(=[C-2]2N(C3C(=CC(C)=CC=3C)C)CCN2C2C(=CC(C)=CC=2C)C)(=[C-2]C2=CC(N(=O)=O)=CC=C2O1C(C)C)[Cl-] | [CAS DataBase Reference]
502964-52-5 |
| Questions And Answer | Back Directory | [Reaction]
- This catalyst is used for an efficient synthesis of HCV Protease Inhibitor, BILN 2061.
- The nitro-Grela catalyst is a stable olefin metathesis initiator active in various ring-closing, cross, and enyne metathesis reactions. Its efficiency has been proven in numerous total syntheses of natural and biologically active compounds, and in material science.
|
| Hazard Information | Back Directory | [Uses]
nitro-Grela is a universal catalyst which provides good results in a wide spectrum of olefin metathesis transformations. The catalyst provides high efficiency in cross metathesis (CM) reactions between type 1 olefins and an electron deficient partner. The catalyst is very good for CM of disubstituted internal olefins. | [reaction suitability]
core: ruthenium
reagent type: catalyst |
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