ChemicalBook--->CAS DataBase List--->514-73-8

514-73-8

514-73-8 Structure

514-73-8 Structure
IdentificationBack Directory
[Name]

3,3'-DIETHYLTHIADICARBOCYANINE IODIDE
[CAS]

514-73-8
[Synonyms]

DEJO
DTDC
DTDCI
DTDCL
DELVEX
NK 136
PARTEL
TELMID
TELMIDE
NETOCYD
ANELMID
l-01748
dejo[qr]
TELMICID
vercidon
nk136[qr]
dizan[qr]
ABMINTHIC
DILOMBRIN
DILOMBRINE
DITHIAZINE
ANGUIFUGAN
DI-S-C2(5)
iodide[qr]
delvex[qr]
partel[qr]
telmid[qr]
miodide[qr]
anelmid[qr]
OMNI-PASSIN
DTDC IODIDE
EASTMAN 7663
nectocyd[qr]
dithiazinine
telmicid[qr]
Dithiazanine
iumiodide[qr]
deselmine[qr]
dilombrin[qr]
abminthic[qr]
AURORA KA-322
COMPOUND 01748
anguifugan[qr]
omni-passin[qr]
DITHIAZINE (DYE)
DITHIAZANIN IODIDE
DITHIAZANINE IODIDE
ossiurene(amsa,italy)[qr]
DIETHYLTHIADICARBOCYANINE IODIDE
Diethylthiodicarbocyanine iodide
3,3'-DIETHYLTHIACARBODICYANINEODIDE
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE
3,3'-DIETHYLTHIA CARBODICYANINE IODIDE
3,3'-DIETHYLDITHIACARBODICYANINE IODIDE
3,3’-diethylthiadicarbocyanineiodide[qr]
3,3-DIETHYLTHIADICARBOCYANINE IODIDE 99%
3,3’-diethylpentamethinethiacyanineiodide
3,3'-DIETHYL-2,2'-THIADICARBOCYANINE IODIDE
3,3'-Diethylthiadicarbocyanine iodide, pure
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE, 9 8%
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE, 99%, PURE
3,3-DIETHYLTHIADICARBOCYANINE IODIDE, LASER GADE 99%
3,3'-Diethylthiadicarbocyanine iodide Dye content 98 %
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE, F OR FLUORESCENCE
3,3'-Diethylthiadicarbocyanine iodide, laser grade, pure
3,3'-Diethylthiadicarbocyanine iodide,99%,pure,laser grade
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE, 99%, LASER GRADE, PURE
Dithiazanine iodide: (3,3'-Diethylpentamethinethiacyanine iodide)
3-ethyl-2-(5-(3-ethyl-2-benzothiazolinylidene)-1,3-pentadienyl)benzothiazoli
3-ethyl-2-(5-(3-ethyl-2-benzothiazolinylidene)-1,3-pentadienyl)benzothiazolium
benzothiazolium,3-ethyl-2-(5-(3-ethyl-2(3h)-benzothiazolylidene)-1,3-pentadien
benzothiazolium,3-ethyl-2-(5-(3-ethyl-2-benzothiazolinylidene)-1,3-pentadienyl
benzothiazolium,3-ethyl-2-[5-(3-ethyl-2(3h)-benzothiazolylidene)-1,3-pentadien
3-ethyl-2-(5-(3-ethyl-2-(3h)-benzothiazolylidene)-1,3-pentadienyl)benzothiazol
3-ethyl-2-(5-(3-ethylbenzothiazol-2(3h)-ylidene)penta-1,3-dienyl)benzothiazoliu
3-ETHYL-2-[5-(3-ETHYL-2-BENZOTHIAZOLINYLIDENE)-1,3-PENTADIENYL]BENZOTHIAZOLIUM IODIDE
3-ETHYL-2-[5-(3-ETHYL-2(3H)-BENZOTHIAZOLYLIDENE)-1,3-PENTADIENYL] BENZOTHIAZOLIUM IODIDE
3-ethyl-2-[5-[3-ethyl-3h-benzothiazol-2-ylidene]-1,3-pentadienyl]-benzothiazolium iodide
BENZOTHIAZOLIUM, 3-ETHYL-2-[5-(3-ETHYL-2-BENZOTHIAZOLINYLIDENE)-1,3-PENTADIENYL]-, IODIDE
3-Ethyl-2-[6-(3-ethyl-3H-benzothiazol-2-ylidene)-hexa-1,3-dienyl]-benzothiazol-3-iuM iodide
2-[5-[3-Ethylbenzothiazole-2(3H)-ylidene]-1,3-pentadienyl]-3-ethylbenzothiazole-3-ium·iodide
3-Ethyl-2-[5-[3-ethylbenzothiazole-2(3H)-ylidene]-1,3-pentadienyl]benzothiazole-3-ium·iodide
3-Ethyl-2-((1E,3E,5E)-5-(3-ethylbenzo[d]thiazol-2(3H)-ylidene)penta-1,3-dien-1-yl)benzo[d]thia
Benzothiazolium, 3-ethyl-2-[5-(3-ethyl-2(3H)-benzothiazolylidene)-1,3-pentadien-1-yl]-, iodide
3-ETHYL-2-(5-[3-ETHYL-1,3-BENZOTHIAZOL-2(3H)-YLIDENE]-1,3-PENTADIENYL)-1,3-BENZOTHIAZOL-3-IUM IODIDE
[EINECS(EC#)]

208-186-7
[Molecular Formula]

C23H23IN2S2
[MDL Number]

MFCD00074829
[MOL File]

514-73-8.mol
[Molecular Weight]

518.48
Chemical PropertiesBack Directory
[Appearance]

GREEN CRYSTALLINE POWDER
[Melting point ]

249 °C (dec.)(lit.)
[storage temp. ]

Poison room
[solubility ]

Soluble in methanol
[form ]

Powder
[color ]

Green
[λmax]

655 nm
[Merck ]

14,3369
[BRN ]

3838938
[InChI]

InChI=1S/C23H23N2S2.HI/c1-3-24-18-12-8-10-14-20(18)26-22(24)16-6-5-7-17-23-25(4-2)19-13-9-11-15-21(19)27-23;/h5-17H,3-4H2,1-2H3;1H/q+1;/p-1
[InChIKey]

MNQDKWZEUULFPX-UHFFFAOYSA-M
[SMILES]

C12C=CC=CC=1S/C(=C/C=C/C=C/C1SC3C=CC=CC=3[N+]=1CC)/N2CC.[I-]
[EPA Substance Registry System]

Dithiazanine iodide (514-73-8)
Hazard InformationBack Directory
[Chemical Properties]

green crystalline powder
[Uses]

Sensitizer for photographic emulsions.
[General Description]

Green, needle-like crystals. Used as a veterinary anthelmintic, as a sensitizer for photographic emulsions and as an insecticides. Not registered as a pesticide in the U.S.
[Reactivity Profile]

An amine, organosulfide. Organosulfides are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.
[Health Hazard]

Highly toxic by mouth. (Non-Specific -- Pesticide, Solid, n.o.s.) Poisonous if swallowed, or if dust is inhaled.
[Fire Hazard]

When heated to decomposition, 3,3'-DIETHYLTHIADICARBOCYANINE IODIDE emits toxic fumes of iodine, sulfur oxides, and nitrogen oxides.
[Description]

Dithiazanine iodide is a green, needle-likecrystalline solid which decomposes at 248℃. Sulfur-likeodor. Molecular weight= 519.51. Melting point 5 225℃;Hazard Identification (based on NFPA-704 M RatingSystem): Health 3, Flammability 0, Reactivity 1. Insolublein water.
[Originator]

Delvex,Lilly,US,1958
[Manufacturing Process]

3.05 g of 1-methylbenzthiazole ethiodide, 1.11 g of β-ethyl thio acrolein diethyl acetal and 15 cc of pyridine were mixed and boiled gently under reflux for 15 minutes. The reaction mixture was then poured into an aqueous solution of potassium iodide. The dye was precipitated and was filtered off, and washed with ethyl alcohol and ether. Recrystallization from methyl alcohol solution yielded the dye as green needles. Melting point 248°C with decomposition.
[Brand name]

Abminthic;Anguifugan;D.i.m.;Deselmine;Dilombrine;Dithiazine (dye);Dizan;Eastman 7663;Elmizin;Nekel;Omni-passin;Ossiurene;Telmicid;Telmide.
[Therapeutic Function]

Anthelmintic
[World Health Organization (WHO)]

Dithiazanine iodide, an anthelminthic, was introduced in 1959 for the treatment of strongyloid worms and whipworms. Between 1961 and 1964 its use was associated with eight fatal cases of severe acidosis and shock. Although the drug is not significantly absorbed from the gut, in normal circumstances it was assumed that these fatalities were due to atypically high uptake from inflamed intestinal mucosa. Dithiazanine iodide has been superseded by safer and more effective drugs; however, it may remain available in some countries.
[Potential Exposure]

This material is used as a plasticizer,as a rubber accelerator; and as an intermediate inmanufacturing of pesticides
[First aid]

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medical attention immediately. If this chemical contacts theskin, remove contaminated clothing and wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, including resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medical attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit.
[storage]

Color Code—Blue: Health Hazard/Poison: Storein a secure poison location. Prior to working with thischemical you should be trained on its proper handling andstorage. Store in tightly closed containers in a cool, wellventilated area.
[Shipping]

Pesticides, solid, toxic, n.o.s. have a labelrequirement of “POISONOUS/TOXIC MATERIALS.”They fall in Hazard Class 6.1 and this material in PackingGroup II.
[Incompatibilities]

Stable under normal conditions of temperature and pressure. Keep away from alkalies, strongoxidizers.
Safety DataBack Directory
[Hazard Codes ]

T+
[Risk Statements ]

28-36/37/38
[Safety Statements ]

26-28-36/37-45
[RIDADR ]

UN 2811 6.1/PG 2
[WGK Germany ]

3
[RTECS ]

DL7060000
[F ]

8
[TSCA ]

Yes
[HazardClass ]

6.1
[PackingGroup ]

II
[HS Code ]

29309099
[Storage Class]

6.1A - Combustible acute toxic Cat. 1 and 2
very toxic hazardous materials
[Hazard Classifications]

Acute Tox. 2 Oral
Eye Irrit. 2
Skin Irrit. 2
STOT SE 3
[Safety Profile]

Poison by ingestion, intraperitoneal, and intravenous routes. When heated to decomposition it emits very toxic fumes of I-, SOx, and NOx. See also IODIDES.
[Hazardous Substances Data]

514-73-8(Hazardous Substances Data)
[Toxicity]

LD50 intraperitoneal in mouse: 3mg/kg
Spectrum DetailBack Directory
[Spectrum Detail]

3,3'-DIETHYLTHIADICARBOCYANINE IODIDE(514-73-8)1HNMR
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE(514-73-8)IR1
3,3'-DIETHYLTHIADICARBOCYANINE IODIDE(514-73-8)IR2
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