Identification | Back Directory | [Name]
DIMETHYLBORON BROMIDE | [CAS]
5158-50-9 | [Synonyms]
(CH3)2BBr BROMODIMETHYLBORANE DIMETHYLBORON BROMIDE Borane, bromodimethyl- Bromodimethylborane, 97%, Dimethylboron bromide, 97+% Borane, bromodimethyl- (7CI,8CI,9CI) | [Molecular Formula]
C2H6BBr | [MDL Number]
MFCD00000053 | [MOL File]
5158-50-9.mol | [Molecular Weight]
120.78 |
Chemical Properties | Back Directory | [Melting point ]
-129°C | [Boiling point ]
31-32°C | [density ]
1,238 g/cm3 | [vapor pressure ]
10.4 psi ( 20 °C) | [Fp ]
-37°C | [refractive index ]
1.399 | [storage temp. ]
2-8°C | [solubility ]
sol dichloromethane, 1,2-dichloroethane, hexane. | [form ]
Liquid | [Sensitive ]
Air & Moisture Sensitive | [BRN ]
1730828 |
Hazard Information | Back Directory | [Reactivity Profile]
Dimethylboron bromide is a mild Lewis acid capable of selective cleavage of ethers and acetals; deoxygenation of sulfoxides.
| [Synthesis]
Dimethylboron bromide can be conveniently prepared by treating Tetramethylstannane with Boron Tribromide.
| [Precautions]
Dimethylboron bromide is a flammable liquid, moisture sensitive; typically stored and dispensed as a 1.5-2 M solution in dichloromethane or dichloroethane. Solutions of this sort are stable for a period of months if stored at -15 °C and properly protected from moisture.
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