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52801-27-1

52801-27-1 Structure

52801-27-1 Structure
IdentificationBack Directory
[Name]

(+)-2,3-Dimethoxy-6-[[(5R)-5,6,7,8-tetrahydro-6-methyl-1,3-dioxolo[4,5-g]isoquinoline-5-yl]methyl]benzaldehyde
[CAS]

52801-27-1
[Synonyms]

Nsc279521
Canadaline
(S)-(+)-Canadaline
2,3-dimethoxy-6-[[(5S)-6-methyl-7,8-dihydro-5H-[1,3]dioxolo[4,5-g]isoquinolin-5-yl]methyl]benzaldehyde
Benzaldehyde, 2,3-dimethoxy-6-[[(5S)-5,6,7,8-tetrahydro-6-methyl-1,3-dioxolo[4,5-g]isoquinolin-5-yl]methyl]-
(+)-2,3-Dimethoxy-6-[[(5R)-5,6,7,8-tetrahydro-6-methyl-1,3-dioxolo[4,5-g]isoquinolin-5-yl]methyl]benzaldehyde
(+)-2,3-Dimethoxy-6-[[(5R)-5,6,7,8-tetrahydro-6-methyl-1,3-dioxolo[4,5-g]isoquinoline-5-yl]methyl]benzaldehyde
[Molecular Formula]

C21H23NO5
[MDL Number]

MFCD30720038
[MOL File]

52801-27-1.mol
[Molecular Weight]

369.41
Chemical PropertiesBack Directory
[Melting point ]

117-8°C
[storage temp. ]

-20°C Freezer
[solubility ]

Acetonitrile (Slightly), Chloroform (Slightly), Methanol (Slightly, Heated)
[form ]

Solid
[color ]

Off-White to Pale Beige
Hazard InformationBack Directory
[Description]

One of a number of alkaloids obtained from Hydrastis canadensis, this base has recently been isolated and characterized. It crystallizes as colourless needles from Et20 and has a specific rotation of [α]D + 43° (c 0.5, CHC13). The ultraviolet spectrum in EtOH consists of a single absorption maximum at 288 nm. The structure of canadaline has been established from spectroscopic data.
[Chemical Properties]

Beige Solid
[Uses]

(S)-(+)-Canadaline is an alkaloid isolated from Goldenseal plant, Fumariaceae and various other plant species.
[References]

Gleye, Ahond, Stanislas, Phytochem., 13,675 (1974)
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