| Identification | Back Directory | [Name]
2-methylsulfonylbenzaldehyde | [CAS]
5395-89-1 | [Synonyms]
2-mesylbenzaldehyde
2-methylsulfonylbenzaldehyde
2-Methanesulfonylbenzaldehyde
Benzaldehyde,2-(Methylsulfonyl)-
2-(Methylsulfonyl)-Benzaldehyde 97% | [Molecular Formula]
C8H8O3S | [MDL Number]
MFCD11052332 | [MOL File]
5395-89-1.mol | [Molecular Weight]
184.21 |
| Chemical Properties | Back Directory | [Melting point ]
98-99 °C(Solv: water (7732-18-5)) | [Boiling point ]
385.7±34.0 °C(Predicted) | [density ]
1.289±0.06 g/cm3(Predicted) | [storage temp. ]
2-8°C, stored under nitrogen | [form ]
solid | [Appearance]
White to off-white Solid |
| Hazard Information | Back Directory | [Synthesis]
2-Fluorobenzaldehyde (12.4 g, 0.1 mol, 1 eq.) and methanesulfonic acid (11.2 g, 0.11 mol, 1.1 eq.) were dissolved in DMSO (75 ml) and heated to 100 °C for 16 hours. After completion of the reaction, the mixture was cooled to room temperature and poured into crushed ice (100 g). The resulting 2-(methylsulfonyl)benzaldehyde was collected by filtration and dried under vacuum at 45 °C for 16 h to give a yellow solid product (9.2 g, 50% yield). The product was characterized as follows: 1H NMR (300 MHz, CDCl3) δ 10.77 (1H, s, CHO), 8.18-8.16 (1H, m, ArH), 8.10-8.08 (1H, m, ArH), 7.83-7.80 (2H, m, ArH), 3.28 (3H, s, SO2CH3); LCMS (6 min) Rt = 1.93 min, (M++1) = 185.1. | [References]
[1] Patent: WO2004/52858, 2004, A2. Location in patent: Page 109 |
|
| Company Name: |
SynAsst Chemical.
|
| Tel: |
021-60343070 |
| Website: |
www.chemicalbook.com/ShowSupplierProductsList15848/0_EN.htm |
|