ChemicalBook--->CAS DataBase List--->540475-45-4

540475-45-4

540475-45-4 Structure

540475-45-4 Structure
IdentificationBack Directory
[Name]

1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97%
[CAS]

540475-45-4
[Synonyms]

R,R-Me-Ferrocelane
1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97%
1,1'-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ferrocene, 97+%
(+)-1,1'-Bis[(2R,5R)-2,5-dimethylphospholano]ferrocene, 97% (R,R-Me-Ferrocelane)
[Molecular Formula]

C22H32FeP2
[MDL Number]

MFCD08705241
[MOL File]

540475-45-4.mol
[Molecular Weight]

406.23
Chemical PropertiesBack Directory
[Melting point ]

99-102℃
[storage temp. ]

under inert gas (nitrogen or Argon) at 2-8°C
[form ]

solid
[color ]

yellow
[Water Solubility ]

Insoluble in water.
[Sensitive ]

Air Sensitive
[InChI]

1S/2C11H21P.2CH3.Fe/c2*1-9-7-8-10(2)12(9)11-5-3-4-6-11;;;/h2*9-11H,3-8H2,1-2H3;2*1H3;/t2*9-,10-;;;/m11.../s1
[InChIKey]

TZPGMNOFYCAGIA-UIBZXYQVSA-N
[SMILES]

C[Fe]C.C[C@@H]1CC[C@@H](C)P1[C@H]2CCCC2.C[C@@H]3CC[C@@H](C)P3[C@@H]4CCCC4
Safety DataBack Directory
[Symbol(GHS) ]

GHS hazard pictograms
GHS07
[Signal word ]

Warning
[Hazard statements ]

H302-H315-H319-H335
[Precautionary statements ]

P261-P280-P301+P312-P302+P352-P305+P351+P338
[WGK Germany ]

3
[Storage Class]

11 - Combustible Solids
Questions And AnswerBack Directory
[Reaction]

  1. Ligand for the palladium-catalyzed, atroposelective C–P coupling process for the asymmetric synthesis of QUINAP and its derivatives.
  2. Ligand for rhodium driven hydroaminomethylation involving styrene and piperidine.
Reactions of 540475-45-4
Hazard InformationBack Directory
[Uses]

DuPhos and BPE Ligands: Highly Efficient Privileged Ligands
Spectrum DetailBack Directory
[Spectrum Detail]

1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97%(540475-45-4)1HNMR
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