| Identification | Back Directory | [Name]
1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97% | [CAS]
540475-45-4 | [Synonyms]
R,R-Me-Ferrocelane 1,1Bis((2R,5R)-2,5-dimethylphospholano)ferrocene, min. 97% 1,1'-Bis[(2R,5R)-2,5-diMethyl-1-phospholanyl]ferrocene, 97+% (+)-1,1'-Bis[(2R,5R)-2,5-dimethylphospholano]ferrocene, 97% (R,R-Me-Ferrocelane) | [Molecular Formula]
C22H32FeP2 | [MDL Number]
MFCD08705241 | [MOL File]
540475-45-4.mol | [Molecular Weight]
406.23 |
| Chemical Properties | Back Directory | [Melting point ]
99-102℃ | [storage temp. ]
under inert gas (nitrogen or Argon) at 2-8°C | [form ]
solid | [color ]
yellow | [Water Solubility ]
Insoluble in water. | [Sensitive ]
Air Sensitive | [InChI]
1S/2C11H21P.2CH3.Fe/c2*1-9-7-8-10(2)12(9)11-5-3-4-6-11;;;/h2*9-11H,3-8H2,1-2H3;2*1H3;/t2*9-,10-;;;/m11.../s1 | [InChIKey]
TZPGMNOFYCAGIA-UIBZXYQVSA-N | [SMILES]
C[Fe]C.C[C@@H]1CC[C@@H](C)P1[C@H]2CCCC2.C[C@@H]3CC[C@@H](C)P3[C@@H]4CCCC4 |
| Questions And Answer | Back Directory | [Reaction]
- Ligand for the palladium-catalyzed, atroposelective C–P coupling process for the asymmetric synthesis of QUINAP and its derivatives.
- Ligand for rhodium driven hydroaminomethylation involving styrene and piperidine.
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