| Identification | Back Directory | [Name]
THALSIMIDINE ME ETHER | [CAS]
5525-36-0 | [Synonyms]
C09661
ME ETHER
Thalsimine
THALSIMIDINE ME ETHER
16H-1,24:6,9-Dietheno-11,15-metheno-2H-pyrido[2',3':17,18][1,11]dioxacycloeicosino[2,3,4-ij]isoquinoline, 3,5,16a,17,18,19-hexahydro-12,20,21,22,26-pentamethoxy-17-methyl-, (16aS)- | [Molecular Formula]
C38H40N2O7 | [MDL Number]
MFCD09837977 | [MOL File]
5525-36-0.mol | [Molecular Weight]
636.73 |
| Hazard Information | Back Directory | [Description]
A further bisbenzylisoquinoline alkaloid from the above ground parts of Thalictrum simplex, this base is separated from the accompanying thalsimidine by thin layer chromatography. It is also dextrorotatory having [o:ll,0 + 27.45° (c 6.72, CHCI 3 ). The crystalline hydrochloride decomposes at 233-5°C and thepicrate, light yellow needles, also decomposes before melting, at 209-21 1°C.
The original structure has subsequently been revised to that given above. | [Definition]
ChEBI: Thalsimine is a member of isoquinolines. | [References]
Ismailov, Maekh, Yunusov., Dokl. Akad. Nauk. Uzbek SSR, 12, 22 (1960)
Maekh, Yunusov., ibid, 21,27 (1964)
Shamma et al., Chem. Commun., 7 (1966) |
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