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5565-32-2

5565-32-2 Structure

5565-32-2 Structure
IdentificationBack Directory
[Name]

CHLOROTRIS(TRIMETHYLSILYL)SILANE
[CAS]

5565-32-2
[Synonyms]

CHLOROTRIS(TRIMETHYLSILYL)SILANE
Tris(Trimethylsilyl) Chlorosilane
Tris(trimethylsilyl)silyl Chloride
Chlorotris(trimethylsilyl)silane 97%
Chlorotris(trimethylsilyl)silane >
Chlorotris(trimethylsilyl)silane solution
1,1,1,3,3,3-Hexamethyl-2-(trimethylsilyl)-2-chlorotrisilane
Trisilane, 2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-
[Molecular Formula]

C9H27ClSi4
[MDL Number]

MFCD01321222
[MOL File]

5565-32-2.mol
[Molecular Weight]

283.11
Chemical PropertiesBack Directory
[Melting point ]

50-52 °C(lit.)
[Boiling point ]

93°C/1.8mmHg(lit.)
[density ]

0.877 g/mL at 25 °C
[Fp ]

87 °F
[form ]

powder to lump
[color ]

White to Almost white
[Hydrolytic Sensitivity]

8: reacts rapidly with moisture, water, protic solvents
[InChI]

1S/C9H27ClSi4/c1-11(2,3)14(10,12(4,5)6)13(7,8)9/h1-9H3
[InChIKey]

HCOROOJWVHFMRJ-UHFFFAOYSA-N
[SMILES]

C[Si](C)(C)[Si](Cl)([Si](C)(C)C)[Si](C)(C)C
Safety DataBack Directory
[Hazard Codes ]

F,C,Xn,Xi
[Risk Statements ]

11-29-34-67-65-48/20-36/37/38-63
[Safety Statements ]

16-26-36/37/39-43-45-7/8-62-36/37-Neverusewater.
[RIDADR ]

UN 2925 4.1/PG 2
[WGK Germany ]

3
[HS Code ]

2931.90.9010
[HazardClass ]

4.1/8
[PackingGroup ]

II
[Storage Class]

4.3 - Hazardous materials which set free flammable gases upon contact with water
[Hazard Classifications]

Eye Irrit. 2
Flam. Sol. 1
Skin Irrit. 2
STOT SE 3
Water-react 3
Hazard InformationBack Directory
[Uses]

Super Silyl Protecting Groups

Used for:
  • Insertion into a P-P bond
  • Diastereoselective aldol and cascade reactions
  • Preparation of hypersilyl substituted monophosphines and diphosphines
[General Description]

Chlorotris(trimethylsilyl)silane is an organosilicon reagent, which is generally employed in the protection of alcohols. It is also used to prepare organometallic reagents, silyl enol ethers, and novel polymers/materials.
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