ChemicalBook--->CAS DataBase List--->55718-76-8

55718-76-8

55718-76-8 Structure

55718-76-8 Structure
IdentificationBack Directory
[Name]

2-CHLORO-1,3,2-BENZODIOXABOROLE
[CAS]

55718-76-8
[Synonyms]

2-Chlorobenzo[d][1
?Chlorocatecholborane
B-CHLOROCATECHOLBORANE
SS-CHLOROCATECHOLBORANE
iBi-Chlorocatecholborane
BETA-CHLOROCATECHOLBORANE
B-Chlorocatecholborane 97%
2-Chlor-1,3,2-benzodioxaborol
2-CHLORO-1,3,2-BENZODIOXABOROLE
1,3,2-Benzodioxaborole, 2-chloro-
2-Chlorobenzo[d][1,3,2]dioxaborole
2- chloro -1,3,2- benzodioxa boron heterocyclic pentene
[Molecular Formula]

C6H4BClO2
[MDL Number]

MFCD00043395
[MOL File]

55718-76-8.mol
[Molecular Weight]

154.36
Chemical PropertiesBack Directory
[Melting point ]

56-58 °C(lit.)
[Boiling point ]

64 °C(Press: 10 Torr)
[density ]

1.31±0.1 g/cm3(Predicted)
[Fp ]

140 °F
[storage temp. ]

2-8°C
[form ]

powder to crystal
[color ]

White to Light yellow to Light red
[BRN ]

2093985
[InChI]

1S/C6H4BClO2/c8-7-9-5-3-1-2-4-6(5)10-7/h1-4H
[InChIKey]

AZYGEWXDKHFOKB-UHFFFAOYSA-N
[SMILES]

Clb1oc2ccccc2o1
Safety DataBack Directory
[Hazard Codes ]

F,C
[Risk Statements ]

11-14-34-37
[Safety Statements ]

16-26-36/37/39-45
[RIDADR ]

UN 2925 4.1/PG 2
[WGK Germany ]

3
[F ]

10-23
[HS Code ]

2915.40.5050
[HazardClass ]

8
[PackingGroup ]

II
[Storage Class]

4.1B - Flammable solid hazardous materials
[Hazard Classifications]

Flam. Sol. 1
Skin Corr. 1B
STOT SE 3
Hazard InformationBack Directory
[Uses]

B-Chlorocatecholborane can be used:
  • To prepare 2-arachidonoylglycerol by acetal cleavage of cis-arachidonoylbenzylidene glycerol.
  • To prepare metal boryl complexes (Rh and Ir complexes) through oxidative addition.
  • To remove the trityl group in one of the key steps for the synthesis of (?)-dictyostatin.

[General Description]

B-Chlorocatecholborane is a boron reagent and a Lewis acid, known to facilitate the borylative cyclization of alkynes to yield the borylated heterocycles. It is also used in the preparation of lactones, and thiophenes.
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