ChemicalBook--->CAS DataBase List--->5594-30-9

5594-30-9

5594-30-9 Structure

5594-30-9 Structure
IdentificationBack Directory
[Name]

methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
[CAS]

5594-30-9
[Synonyms]

methylpheophorbide
Methylpheophorbide a
Methyl pheophorbide a
Methylphaeophorbide a
PHEOPHORBIDEAMETHYLESTER
Phaeophorbide a methyl ester
Demagnesia chloric acid -a methyl ester
(3S)-9-Ethenyl-14-ethyl-21α-methoxycarbonyl-4α,8,13,18-tetramethyl-20-oxo-3-phorbinepropanoic acid methyl ester
methyl [3S-(3alpha,4beta,21beta]-14-ethyl-21-(methoxycarbonyl)-4,8,13,18-tetramethyl-20-oxo-9-vinylphorbine-3-propionate
[EINECS(EC#)]

227-007-3
[Molecular Formula]

C36H38N4O5
[MOL File]

5594-30-9.mol
[Molecular Weight]

606.71
Chemical PropertiesBack Directory
[Melting point ]

226-228 °C
[Boiling point ]

956.2±65.0 °C(Predicted)
[density ]

1.244±0.06 g/cm3(Predicted)
[form ]

Solid
[color ]

Brown to black
Hazard InformationBack Directory
[Uses]

Methyl pheophorbide a is a natural product, one of the chlorophyll-a derivatives[1][2].
[References]

[1] F.C. Pennington, et al. Preparation and Properties of Pyrochlorophyll a, Methyl Pyrochlorophyllide a, Pyropheophytin a, and Methyl Pyropheophorbide a Derived from Chlorophyll by Decarbomethoxylation. J. Am. Chem. Soc. 1964, 86, 7, 1418-1426.
[2] ShinOgasawara, et al. C132-Methylation of methyl pheophorbide a and stereoselective preparation of methyl (132R)-methylpyropheophorbide a. Tetrahedron Letters, 2014, 3618-3621.
[3] Ha J Y, et al. Isolation, identification, and apoptosis activity of the photosensitizer methyl pheophorbide A from Perilla frutescens leaves[J]. Applied Biological Chemistry, 2022, 65(1): 52.
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