569650-64-2

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569650-64-2 Structure

Identification	Back Directory
[Name] (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE
[CAS] 569650-64-2
[Synonyms] (R,R)-I-PR-DUPHOS-RH 1,2-Bis[(2R,5R)-2,5-diisopropylphospholano]benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 1,2-Bis((2R,5R)-2,5-diisopropylphospholano)benzene(cyclooctadiene)rhodium(I) tetrafluoroborate, 97% (+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate (+)-1,2-BIS((2R,5R)-2,5-DI-I-PROPYLPHOSPHOLANO)BENZENE)1,5-CYCLOOCTADIENE)RHODIUM (I) TETRAFLUOROBORATE (+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene)1,5-cyclooctadiene)rhodium(I)tetrafluoroborate,min.98%(R,R)-i-Pr-DUPHOS-Rh (+)-1,2-Bis((2R,5R)-2,5-di-i-propylphospholano)benzene(1,5-cyclooctadiene) rhodium (I) tetrafluoroborate, min. 98% (R,R)-i-Pr-DUPHOS-Rh
[Molecular Formula] C34H56BF4P2Rh
[MDL Number] MFCD07369039
[MOL File] 569650-64-2.mol
[Molecular Weight] 716.47

Chemical Properties	Back Directory
[form ] Powder
[color ] Yellow to orange to red to brown
[Sensitive ] air sensitive
[CAS DataBase Reference] 569650-64-2

Safety Data	Back Directory
[Symbol(GHS) ] GHS07
[Signal word ] Warning
[Hazard statements ] H319-H335-H315
[Precautionary statements ] P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[WGK Germany ] 3
[HS Code ] 29310099

[Reaction]

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Forms superior catalysts for asymmetric reductive aminations.
Catalyst used for the asymmetric hydrogenation of enol phosphonates.
A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines.
Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO.
Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization.
Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines.
Palladium catalyzed asymmetric phosphination.

Hazard Information	Back Directory
[Uses] DuPhos and BPE Ligands: Highly Efficient Privileged Ligands

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