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57357-20-7

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57357-20-7 Structure

57357-20-7 Structure
IdentificationBack Directory
[Name]

BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97
[CAS]

57357-20-7
[Synonyms]

(di-tert-butylcarbonyloxyiodo)benzol
[BIS(T-BUTYLCARBONYLOXY)IODO] BENZENE
BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97
Bis(tert-butylcarbonyloxy)iodobenzene 97%
Iodine, bis(2,2-dimethylpropanoato-κO)phenyl-
phenyl-l3-iodanediyl bis(2,2-dimethylpropanoate)
2-(2,2-dimethylpropanoyloxy)-3-iodophenyl]2,2-dimethylpropanoate
(Di-tert-butylcarbonyloxyiodo)benzol, 2,2-Dimethylpropanoic acid, phenyliodine complex, Bis(2,2-dimethylpropanoato-O)phenyliodide, Di-(Pivaloyloxy)iodobenzene
[Molecular Formula]

C16H23IO4
[MDL Number]

MFCD08276835
[MOL File]

57357-20-7.mol
[Molecular Weight]

406.254
Chemical PropertiesBack Directory
[Melting point ]

104-109 °C
[storage temp. ]

2-8°C, protect from light, stored under nitrogen
[form ]

powder to crystal
[color ]

White to Light yellow
[InChI]

InChI=1S/C16H23IO4/c1-15(2,3)13(18)20-17(12-10-8-7-9-11-12)21-14(19)16(4,5)6/h7-11H,1-6H3
[InChIKey]

DZKPLZUSZXYHFB-UHFFFAOYSA-N
[SMILES]

C1C=CC=C(I(OC(=O)C(C)(C)C)OC(=O)C(C)(C)C)C=1
Safety DataBack Directory
[WGK Germany ]

3
[HS Code ]

2931.90.6000
[Storage Class]

11 - Combustible Solids
Hazard InformationBack Directory
[Uses]

Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination

Reagent for:
  • Preparation of α,β-unsaturated-γ-lactams via Rh-catalyzed C-H amination of allene carbamates, then Ru-catalyzed cyclocarbonylation
  • Palladium-catalyzed diamination
  • Preparation of functionalized bicyclic heterocyclic compounds by rhodium-catalyzed allene amidation and cyclization
  • Preparation of piperidine and pyrrolidine derivatives via copper-catalyzed intramolecular aminoacetoxylation of aminoolefins
  • C-H acyloxylation of arenes

  • Hypervalent iodine oxidant
[reaction suitability]

reagent type: catalyst
reaction type: C-H Activation
reagent type: oxidant
Spectrum DetailBack Directory
[Spectrum Detail]

BIS(TERT-BUTYLCARBONYLOXY)IODOBENZENE 97(57357-20-7)1HNMR
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