| Identification | Back Directory | [Name]
2-[(Trifluoromethyl)sulfonyl]-pyridine | [CAS]
57830-55-4 | [Synonyms]
2-Pyridyl trifluoromethyl sulfone
2-[(Trifluoromethyl)sulfonyl]-pyridine
2~ ((trifluoromethyl) sulfonyDp yridine
Pyridine, 2-[(trifluoromethyl)sulfonyl]- | [Molecular Formula]
C6H4F3NO2S | [MOL File]
57830-55-4.mol | [Molecular Weight]
211.16 |
| Hazard Information | Back Directory | [Chemical Properties]
white solid
| [Definition]
Trifluoromethylation is not only achieved with 2-benzo- [d]thiazolyl sulfone, but also by using 2-[(Trifluoromethyl)sulfonyl]-pyridine with a less electron-deficient 2-pyridyl group owing to the stronger electron-withdrawing ability of the attached trifluoromethyl group.
| [Reactions]
Fluoroalkylation of isocyanides with various 2-[(Trifluoromethyl)sulfonyl]-pyridine
![2-[(Trifluoromethyl)sulfonyl]-pyridine](/NewsImg/2024-01-22/6384152768398980177507383.jpg "2-[(Trifluoromethyl)sulfonyl]-pyridine")
| [References]
[1] JIAN RONG. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis[J]. Angewandte Chemie International Edition, 2016, 558: 2743-2747. DOI:10.1002/anie.201510533.
|
|
|