| Identification | Back Directory | [Name]
DIETHYLALUMINUM CYANIDE SOLUTION | [CAS]
5804-85-3 | [Synonyms]
Einecs 227-359-8
(Cyano-C)diethyL
Cyanodiethylalane
Cyanodiethylaluminum
Diethylcyanoaluminum
(cyano-C)diethylaluminium
Aluminum, (cyano-kC)diethyl-
DIETHYLALUMINUM CYANIDE SOLUTION
Aluminum, (cyano-.kappa.C)diethyl-
Diethylaluminum cyanide solution 1.0 in toluene
Diethylaluminum cyanide solution 1.0 M in toluene
DIETHYLALUMINUM CYANIDE SOLUTION, ~1 M I N TOLUENE
DIETHYLALUMINUM CYANIDE, 1.0M SOLUTION I N TOLUENE
D**Diethylaluminum cyanide solution, 1 M in toluene
Diethylaluminum cyanide solution technical, ~1 in tolu | [EINECS(EC#)]
227-359-8 | [Molecular Formula]
C5H10AlN | [MDL Number]
MFCD00001764 | [MOL File]
5804-85-3.mol | [Molecular Weight]
111.121 |
| Chemical Properties | Back Directory | [Boiling point ]
150 °C(Press: 0.07 Torr) | [density ]
0.87 g/mL at 20 °C | [Fp ]
45 °F | [solubility ]
solution in benzene, toluene, diisopropyl ether. | [form ]
syrup | [color ]
colorless | [BRN ]
3587410 |
| Hazard Information | Back Directory | [Uses]
DIETHYLALUMINUM CYANIDE SOLUTION Reagents used to hydrocyanate side chain ketones directed by aryl sulfinyl groups.1
| [Application]
Diethylaluminum Cyanide is used for hydrocyanation of α,β-unsaturated ketones;[1] preparation of α-cyanohydrins from carbonyl compounds.[2] | [Preparation]
Diethylaluminum Cyanide is prepared by reaction of Triethylaluminum with a slight excess of Hydrogen Cyanide below rt[3]. | [storage]
Diethylaluminum Cyanide is highly toxic. It can be stored as 1-2 M solutions in benzene, toluene, or
diisopropyl ether. Use in a fume hood. | [References]
1. Nagata, W.; Yoshioka, M.; Hirai, S. JACS 1972, 94, 4635.
2. Agosta, W. C.; Lowrance, W. W., Jr. JOC 1970, 35, 3851.
3. Nagata, W.; Yoshioka, M. OR 1977, 25, 255.
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| Company Name: |
3A Chemicals
|
| Tel: |
400-668-9898 |
| Website: |
www.3achem.com |
| Company Name: |
Energy Chemical
|
| Tel: |
021-58432009 400-005-6266 |
| Website: |
http://www.energy-chemical.com |
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