| Identification | Back Directory | [Name]
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97% | [CAS]
60261-46-3 | [Synonyms]
(2S)-2-[(Diphenylphosphino)methyl]pyrrolidine
diphenyl-[[(2S)-pyrrolidin-2-yl]methyl]phosphane
(S)-2-((Diphenylphosphino)Methyl)pyrrolidine, 97%
Pyrrolidine, 2-[(diphenylphosphino)methyl]-, (2S)-
(S)-(-)-2-(DiphenylphosphinoMethyl)pyrrolidine, 97+%
(S)-2-[(DIPHENYLPHOSPHINO)METHYL]PYRROLIDINE,MIN.97%
(S)-2-[(Diphenylphosphino)methyl]pyrrolidine, min. 97% | [Molecular Formula]
C17H20NP | [MDL Number]
MFCD16621443 | [MOL File]
60261-46-3.mol | [Molecular Weight]
269.321 |
| Chemical Properties | Back Directory | [Boiling point ]
387.1±15.0 °C(Predicted) | [density ]
1.043 g/mL at 25 °C | [refractive index ]
n20/D1.614 | [Fp ]
>110℃ | [storage temp. ]
2-8°C, protect from light, stored under nitrogen | [form ]
Liquid | [pka]
10.46±0.10(Predicted) | [color ]
Colorless to yellow to tan | [Optical Rotation]
[α]22/D 24.0°, c = 0.5 in ethanol | [Sensitive ]
air sensitive | [InChI]
InChI=1S/C17H20NP/c1-3-9-16(10-4-1)19(14-15-8-7-13-18-15)17-11-5-2-6-12-17/h1-6,9-12,15,18H,7-8,13-14H2/t15-/m0/s1 | [InChIKey]
IWRBGJKCDORZHK-HNNXBMFYSA-N | [SMILES]
N1CCC[C@H]1CP(C1=CC=CC=C1)C1=CC=CC=C1 |
| Hazard Information | Back Directory | [Uses]
Catalytic ligand in:
- Ru-catalyzed regioselective lactonization of unsymmetrical 1,4-diols to give lactone lignans
- Preparation of vinylindanecarboxaldehyde by asymmetric intramolecular allylation of propenylbenzenepropanal
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