ChemicalBook--->CAS DataBase List--->60469-70-7

60469-70-7

60469-70-7 Structure

60469-70-7 Structure
IdentificationBack Directory
[Name]

tert-butylamine hydrobromide
[CAS]

60469-70-7
[Synonyms]

Nsc225071
tert-butylamine hydrobromide
tert-Butylamine Hydrobromide
[EINECS(EC#)]

262-253-5
[Molecular Formula]

C4H12BrN
[MDL Number]

MFCD00674188
[MOL File]

60469-70-7.mol
[Molecular Weight]

154.049
Chemical PropertiesBack Directory
[Water Solubility ]

Soluble in water
[form ]

powder to crystal
[color ]

Powder/crystals
Hazard InformationBack Directory
[Description]

Bearing a?tert-butyl bulky group, t-butylammonium bromide (tBABr) is commonly used to alter perovskite structures to promote material solubility and device stability - by making them less sensitive to moisture (compared to 3D methylammonium-based perovskites).
[Uses]

Organohalide based perovskites have emerged as an important class of material for solar cell applications. Our perovskites precursors are useful for synthesizing mixed cation or anion perovskites needed for the optimization of the band gap, carrier diffusion length and power conversion efficiency of perovskites based solar cells.
[Purification Methods]

Recrystallise the salt several times from absolute EtOH or by dissolving in absolute EtOH and adding Et2O slowly to crystallise the salt. Dry it thoroughly at 105o. [IR: Chenon & Sandorfy Can J Chem 36 1181 1958, Beilstein 4 IV 659.]
Safety DataBack Directory
[Symbol(GHS) ]


GHS07
[Signal word ]

Warning
[Hazard statements ]

H319-H315
[Precautionary statements ]

P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
[HS Code ]

2921.29.0055
Questions And AnswerBack Directory
[Applications]

Bearing a tert-butyl bulky group, t-butylammonium bromide (tBABr) is commonly used to alter perovskite structures to promote material solubility and device stability - by making them less sensitive to moisture (compared to 3D methylammonium-based perovskites).
Plate-like 2D-phase crystallites were observed standing up between the 3D perovskite grains, and crystallinity was remarkably enhanced by precursors with bulky alkyl groups present in the perovskite structure.
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